Application of organoselenides in the Suzuki, Negishi, Sonogashira and Kumada cross-coupling reactions

被引：49
|
作者：
Stein, A. L. [1 ]
Bilheri, F. N. [1 ]
Zeni, G. [1 ]
机构：
[1] CCNE, UFSM, Lab Sintese Reatividade Avaliacao Farmacol & Texi, BR-97105900 Santa Maria, RS, Brazil
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 85期
关键词：
COPPER-CATALYZED SYNTHESIS; DIPHENYL DISELENIDE; ARYLBORONIC ACIDS; SE-SE; DIARYL DISULFIDES; ARYL IODIDE; BOND; CLEAVAGE; DICHALCOGENIDES; CHALCOGENATION;
D O I：
10.1039/c5cc06347g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We reported herein the regio- and stereoselective palladium-catalyzed cross-coupling reactions of unsaturated organoselenides with Sonogashira, Suzuki, Negishi and Kumada partners. The reactions were in general carried out with Pd(PPh3)(4) (10 mol%), in DMF at 80 degrees C to afford the cross-coupling products in good yields. This strategy tolerated a wide range of substrates, such as alkynyl, vinyl, aryl and heteroaryl selenides with a variety of sensitive functional groups and gave the cross-coupling products in good yields.
引用
收藏
页码：15522 / 15525
页数：4
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