Palladium-Catalyzed Decarboxylative C-H Bond Arylation of Furans

被引：31
|
作者：
Pei, Kai [1 ,2 ]
Jie, Xiaoming [2 ]
Zhao, Huaiqing [2 ]
Su, Weiping [1 ,2 ]
机构：
[1] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China
[2] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 20期
基金：
中国国家自然科学基金;
关键词：
Synthetic methods; Cross-coupling; Decarboxylation; C-H arylation; Palladium; CARBOXYLIC-ACIDS; ARYL HALIDES; BENZOIC-ACIDS; VERSATILE CATALYST; OLEFINATION; ARENES; AMIDATION; COUPLINGS; ACYLATION; SULFIDES;
D O I：
10.1002/ejoc.201402278
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Pd/PCy3/Ag2CO3 (Cy = cyclohexyl) catalytic system was found to promote decarboxylative arylation through the combination of decarboxylation and C-H bond functionalization. This protocol features a good substrate scope of aromatic carboxylic acids as well as a broad range of functional groups and provides the products in high yields.
引用
下载
收藏
页码：4230 / 4233
页数：4
相关论文
共 50 条
  • [1] Palladium-Catalyzed Decarboxylative C-H Bond Arylation of Thiophenes
    Hu, Peng
    Zhang, Min
    Jie, Xiaoming
    Su, Weiping
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (01) : 227 - 231
  • [2] Palladium-Catalyzed Decarboxylative Arylation of C-H Bonds by Aryl Acylperoxides
    Yu, Wing-Yiu
    Sit, Wing Nga
    Zhou, Zhongyuan
    Chan, Albert S. -C.
    ORGANIC LETTERS, 2009, 11 (15) : 3174 - 3177
  • [3] Palladium-catalyzed C-H bond arylation with aryl chlorides
    Chiong, Hendrich A.
    Daugulis, Olafs
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [4] Palladium-catalyzed alkenation of thiophenes and furans by regioselective C-H bond functionalization
    Zhao, Jinlong
    Huang, Lehao
    Cheng, Kai
    Zhang, Yuhong
    TETRAHEDRON LETTERS, 2009, 50 (23) : 2758 - 2761
  • [5] Palladium-catalyzed Direct C-H Bond Arylation of Simple Arenes with Aryltrimethylsilanes
    Funaki, Kenji
    Kawai, Hiroshi
    Sato, Tetsuo
    Oi, Shuichi
    CHEMISTRY LETTERS, 2011, 40 (09) : 1050 - 1052
  • [6] Palladium-Catalyzed Electrooxidative Double C-H Arylation
    Lin, Zhipeng
    Oliveira, Joao C. A.
    Scheremetjew, Alexej
    Ackermann, Lutz
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 146 (01) : 228 - 239
  • [7] Palladium-Catalyzed Direct C-H Arylation of Dicyanobenzenes
    Ihanainen, Netta E.
    Kumpulainen, Esa T. T.
    Koskinen, Ari M. P.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2015, 2015 (15) : 3226 - 3229
  • [8] Palladium-Catalyzed Benzylic C-H Arylation of Azaarylmethylamines
    Kim, Byeong-Seon
    Jimenez, Jacqueline
    Gao, Feng
    Wash, Patrick J.
    ORGANIC LETTERS, 2015, 17 (23) : 5788 - 5791
  • [9] Palladium-catalyzed direct arylation of furans via C-H functionalization at low catalyst loadings
    Battace, Ahmed
    Lemhadri, Mhamed
    Zair, Touriya
    Doucet, Henri
    Santelli, Maurice
    ORGANOMETALLICS, 2007, 26 (03) : 472 - 474
  • [10] Palladium-Catalyzed Direct Arylation of Azulene Based on Regioselective C-H Bond Activation
    Murai, Masahito
    Yanagawa, Mayu
    Nakamura, Masahiro
    Takai, Kazuhiko
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 5 (05) : 629 - 635
12345