Palladium-Catalyzed Decarboxylative C-H Bond Arylation of Furans

被引：31
|
作者：
Pei, Kai [1 ,2 ]
Jie, Xiaoming [2 ]
Zhao, Huaiqing [2 ]
Su, Weiping [1 ,2 ]
机构：
[1] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China
[2] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 20期
基金：
中国国家自然科学基金;
关键词：
Synthetic methods; Cross-coupling; Decarboxylation; C-H arylation; Palladium; CARBOXYLIC-ACIDS; ARYL HALIDES; BENZOIC-ACIDS; VERSATILE CATALYST; OLEFINATION; ARENES; AMIDATION; COUPLINGS; ACYLATION; SULFIDES;
D O I：
10.1002/ejoc.201402278
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Pd/PCy3/Ag2CO3 (Cy = cyclohexyl) catalytic system was found to promote decarboxylative arylation through the combination of decarboxylation and C-H bond functionalization. This protocol features a good substrate scope of aromatic carboxylic acids as well as a broad range of functional groups and provides the products in high yields.
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页码：4230 / 4233
页数：4
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