In Situ Generation of Ru Nanoparticles to Catalyze CO2 Hydrogenation to Formic Acid

被引：39
|
作者：
Srivastava, Vivek [1 ]
机构：
[1] NIIT Univ, NH-8 Jaipur Delhi Highway, Neemrana 301705, Rajasthan, India
来源：
CATALYSIS LETTERS | 2014年 / 144卷 / 10期
关键词：
Ru nanoparticles; Ionic liquid; Formic acid; Carbon sequestration; Carbon dioxide; IONIC LIQUIDS; RUTHENIUM CATALYSTS; ROOM-TEMPERATURE; CARBON-DIOXIDE; PARTICLES;
D O I：
10.1007/s10562-014-1321-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Narrow size distributed, stable, catalytically active Ru NPs were synthesis in ionic liquid medium. In situ generated Ru NPs in [DAMI][NTf2] ionic liquid was found highly active in terms of formic acid formed during the CO2 hydrogenation reaction to other ionic liquid immobilized standing Ru NPs. Low catalyst loading, ligand free approach; simple reaction protocol and seven times catalyst recycling are major merits of the proposed work.
引用
收藏
页码：1745 / 1750
页数：6
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