In Situ Generation of Ru Nanoparticles to Catalyze CO2 Hydrogenation to Formic Acid

被引：39
|
作者：
Srivastava, Vivek [1 ]
机构：
[1] NIIT Univ, NH-8 Jaipur Delhi Highway, Neemrana 301705, Rajasthan, India
来源：
CATALYSIS LETTERS | 2014年 / 144卷 / 10期
关键词：
Ru nanoparticles; Ionic liquid; Formic acid; Carbon sequestration; Carbon dioxide; IONIC LIQUIDS; RUTHENIUM CATALYSTS; ROOM-TEMPERATURE; CARBON-DIOXIDE; PARTICLES;
D O I：
10.1007/s10562-014-1321-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Narrow size distributed, stable, catalytically active Ru NPs were synthesis in ionic liquid medium. In situ generated Ru NPs in [DAMI][NTf2] ionic liquid was found highly active in terms of formic acid formed during the CO2 hydrogenation reaction to other ionic liquid immobilized standing Ru NPs. Low catalyst loading, ligand free approach; simple reaction protocol and seven times catalyst recycling are major merits of the proposed work.
引用
收藏
页码：1745 / 1750
页数：6
相关论文
共 50 条
  • [21] Hydrogenation of CO2 to formic acid in the presence of the Wilkinson complex
    N. N. Ezhova
    N. V. Kolesnichenko
    A. V. Bulygin
    E. V. Slivinskii
    S. Han
    Russian Chemical Bulletin, 2002, 51 : 2165 - 2169
  • [22] Hydrogenation of CO2 to formic acid on ruthenium hydroxide catalysts
    Wang, Shengping
    Hao, Cuiying
    Li, Maoshuai
    Kang, Liqiong
    Na, Ping
    Ma, Xinbin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [23] Hydrogenation of CO2 to formic acid in the presence of the Wilkinson complex
    Ezhova, NN
    Kolesnichenko, NV
    Bulygin, AV
    Slivinskii, EV
    Han, S
    RUSSIAN CHEMICAL BULLETIN, 2002, 51 (12) : 2165 - 2169
  • [24] Hydrogenation of CO2 to formic acid on supported ruthenium catalysts
    Hao, Cuiying
    Wang, Shengping
    Li, Maoshuai
    Kang, Liqiong
    Ma, Xinbin
    CATALYSIS TODAY, 2011, 160 (01) : 184 - 190
  • [25] The superiority of Pd2+ in CO2 hydrogenation to formic acid
    Wang, Yanyan
    Dong, Minghua
    Li, Shaopeng
    Chen, Bingfeng
    Liu, Huizhen
    Han, Buxing
    CHEMICAL SCIENCE, 2024, 15 (15) : 5525 - 5530
  • [26] Synthesis of Monometallic Ru/TiO2 Catalysts and Selective Hydrogenation of CO2 to Formic Acid in Ionic Liquid
    Praveenkumar Upadhyay
    Vivek Srivastava
    Catalysis Letters, 2016, 146 : 12 - 21
  • [27] Ru-exchanged MMT Clay with Functionalized Ionic Liquid for Selective Hydrogenation of CO2 to Formic acid
    Srivastava, Vivek
    CATALYSIS LETTERS, 2014, 144 (12) : 2221 - 2226
  • [28] Amine-Functionalized SBA-15 Supported Ru Nanocatalyst for the Hydrogenation CO2 to Formic Acid
    Srivastava, Vivek
    CATALYSIS SURVEYS FROM ASIA, 2021, 25 (02) : 192 - 205
  • [29] Sustainable synthesis of N-doped carbon to stabilize Ru species for CO2 hydrogenation to formic acid
    Lee, Kyung Rok
    Haider, Arsalan
    Park, Kwangho
    Ahn, Sunghee
    Jung, Kwang-Deog
    JOURNAL OF CO2 UTILIZATION, 2024, 86
  • [30] Ru-exchanged MMT Clay with Functionalized Ionic Liquid for Selective Hydrogenation of CO2 to Formic acid
    Vivek Srivastava
    Catalysis Letters, 2014, 144 : 2221 - 2226
12345