Microwave-Assisted Oxidation of Alcohols Using Zinc Polyoxometalate

被引：5
|
作者：
Kasprzyk, Wiktor [1 ]
Galica, Mateusz [1 ]
Bednarz, Szczepan [1 ]
Bogdal, Dariusz [1 ]
机构：
[1] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Biotechnol & Phys Chem, PL-31155 Krakow, Poland
来源：
SYNLETT | 2014年 / 25卷 / 19期
关键词：
oxidation; hydrogen peroxide; catalysis; alcohols; microwave irradiation; MANGANESE-CONTAINING POLYOXOMETALATE; EFFECTIVE CATALYTIC-SYSTEM; CHIRAL ALLYLIC ALCOHOLS; HYDROGEN-PEROXIDE; REGIOSELECTIVE EPOXIDATION; HOMOGENEOUS CATALYSIS; SELECTIVE OXIDATION; EFFICIENT; ALKENES; ACTIVATION;
D O I：
10.1055/s-0034-1379211
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In the presence of 30% aqueous hydrogen peroxide and [WZn3(H2O)(2)][ZnW9O34)(2)](12-) polyoxometalate as a catalyst, primary and secondary alcohols were oxidized to carboxylic acids and ketones, respectively, in short reaction times (ca. 15 min) under microwave-pressurized conditions.
引用
收藏
页码：2757 / 2760
页数：4
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