Microwave-Assisted Oxidation of Alcohols Using Zinc Polyoxometalate

被引：5
|
作者：
Kasprzyk, Wiktor [1 ]
Galica, Mateusz [1 ]
Bednarz, Szczepan [1 ]
Bogdal, Dariusz [1 ]
机构：
[1] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Biotechnol & Phys Chem, PL-31155 Krakow, Poland
来源：
SYNLETT | 2014年 / 25卷 / 19期
关键词：
oxidation; hydrogen peroxide; catalysis; alcohols; microwave irradiation; MANGANESE-CONTAINING POLYOXOMETALATE; EFFECTIVE CATALYTIC-SYSTEM; CHIRAL ALLYLIC ALCOHOLS; HYDROGEN-PEROXIDE; REGIOSELECTIVE EPOXIDATION; HOMOGENEOUS CATALYSIS; SELECTIVE OXIDATION; EFFICIENT; ALKENES; ACTIVATION;
D O I：
10.1055/s-0034-1379211
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In the presence of 30% aqueous hydrogen peroxide and [WZn3(H2O)(2)][ZnW9O34)(2)](12-) polyoxometalate as a catalyst, primary and secondary alcohols were oxidized to carboxylic acids and ketones, respectively, in short reaction times (ca. 15 min) under microwave-pressurized conditions.
引用
收藏
页码：2757 / 2760
页数：4
相关论文
共 50 条
  • [31] Microwave-Assisted Condensation of Benzylic Alcohols and Alkynes Promoted by Zinc Halides: Concise Access to Alkenyl Halides
    Nandi, Poulomi
    Goel, Komal
    Sreenivasulu, Chinnabattigalla
    Satyanarayana, Gedu
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (34) : 4851 - 4860
  • [32] Oxidovanadium complexes with tridentate aroylhydrazone as catalyst precursors for solvent-free microwave-assisted oxidation of alcohols
    Sutradhar, Manas
    Martins, Luisa M. D. R. S.
    Guedes da Silvaa, M. Fatima C.
    Pombeiro, Armando J. L.
    APPLIED CATALYSIS A-GENERAL, 2015, 493 : 50 - 57
  • [33] Solventless microwave-assisted chlorodehydroxylation for the conversion of alcohols to alkyl chlorides
    Reid, MC
    Clark, JH
    Macquarrie, DJ
    GREEN CHEMISTRY, 2006, 8 (05) : 437 - 438
  • [34] Microwave-assisted liquefaction of five types of biomass in polyhydric alcohols
    Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, China
    Chem. Ind. For. Prod., 1 (107-112):
  • [35] Microwave-assisted NiCl2 promoted acylation of alcohols
    Constantinou-Kokotou, V
    Peristeraki, A
    SYNTHETIC COMMUNICATIONS, 2004, 34 (22) : 4227 - 4232
  • [36] Microwave-assisted Solvothermal Synthesis of Bis(nicotinate)zinc
    Gao Fei
    Wang Ying
    Liu Xiao-Yang
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2011, 32 (03): : 678 - 682
  • [37] Facile Microwave-Assisted Synthesis of Zinc Oxide and Characterization
    Bhatta, L. K. Gopalakrishna
    Bhatta, U. M.
    Venkatesh, K.
    JOURNAL OF SCIENTIFIC & INDUSTRIAL RESEARCH, 2019, 78 (03): : 173 - 176
  • [38] Microwave-assisted Synthesis and Characterization of Zinc Oxide Micropowder
    Pookmanee, Pusit
    Makarunkamol, Supasima
    Satienperakul, Sakchai
    Kitikul, Jiraporn
    Phanichphant, Sukon
    FUNCTIONALIZED AND SENSING MATERIALS, 2010, 93-94 : 643 - +
  • [39] Microwave-assisted synthesis of zinc derivatives of potato starch
    Staroszczyk, Hanna
    Janas, Piotr
    CARBOHYDRATE POLYMERS, 2010, 80 (03) : 962 - 969
  • [40] Microwave-Assisted Synthesis of Ultrasmall Zinc Oxide Nanoparticles
    Saloga, Patrick E. J.
    Thuenemann, Andreas F.
    LANGMUIR, 2019, 35 (38) : 12469 - 12482
12345