A cooperative Pd-Cu system for direct C-H bond arylation

被引：57

作者：

Lesieur, Mathieu ^{[1
]}

Lazreg, Faima ^{[1
]}

Cazin, Catherine S. J. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 64期

关键词：

CROSS-COUPLING REACTIONS; SUZUKI-MIYAURA; VINYL HALIDES; PALLADIUM; COMPLEXES; REAGENTS; CATALYST; SUBSTITUTIONS; HETEROARENES; ACTIVATION;

D O I：

10.1039/c4cc03201b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel and efficient method for C-H arylation using well-defined Pd- and Cu-NHC systems has been developed. This process promotes the challenging construction of C-C bonds from arenes or heteroarenes using aryl bromides and chlorides. Mechanistic studies show that [Cu(OH)(NHC)] plays a key role in the C-H activation and is involved in the transmetallation with the Pd-NHC co-catalyst.

引用

下载

页码：8927 / 8929

页数：3

共 50 条

[31] Direct C-H arylation of purines and purine nucleosides
Cerna, Igor
Hocek, Michal
CHEMISTRY OF NUCLEIC ACID COMPONENTS, 2008, 10 : 327 - 329
[32] The first direct C-H arylation of purine nucleosides
Cerna, Igor
Pohl, Radek
Hocek, Michal
CHEMICAL COMMUNICATIONS, 2007, (45) : 4729 - 4730
[33] Palladium-Catalyzed Direct Arylation of Azulene Based on Regioselective C-H Bond Activation
Murai, Masahito
Yanagawa, Mayu
Nakamura, Masahiro
Takai, Kazuhiko
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 5 (05) : 629 - 635
[34] Orthogonal Palladium-Catalyzed Direct C-H Bond Arylation of Heteroaromatics with Aryl Halides
Theveau, Laure
Schneider, Cedric
Fruit, Corinne
Hoarau, Christophe
CHEMCATCHEM, 2016, 8 (20) : 3183 - 3194
[35] Pd-Catalyzed direct C-H arylation of pyrrolo[1,2-a]quinoxalines
Hao, Di
Yang, Zhen
Liu, Yali
Li, Yang
Li, Chuntian
Gu, Yanlong
Vaccaro, Luigi
Liu, Jichang
Liu, Ping
ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (04) : 847 - 851
[36] Ligand Combination Approach in Pd-Catalyzed Direct C-H Arylation of Benzothiazole and Benzoxazole
Bakare, Sneha Prasad
Patil, Mahendra
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (02)
[37] Rhodium-Catalyzed C-H Bond Arylation of Arenes
Bouffard, Jean
Itami, Kenichiro
C-H ACTIVATION, 2010, 292 : 231 - 280
[38] Iridium Catalysis for C-H Bond Arylation of Heteroarenes with lodoarenes
Join, Benoit
Yamamoto, Takuya
Itami, Kenichiro
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (20) : 3644 - 3647
[39] Direct C-H bond arylation:: Selective palladium-catalyzed C2-arylation of N-substituted indoles
Lane, BS
Sames, D
ORGANIC LETTERS, 2004, 6 (17) : 2897 - 2900
[40] Direct C-H Allylation of Unactivated Alkanes by Cooperative W/Cu Photocatalysis
Martinez-Balart, Pol
Toth, Balazs L.
Velasco-Rubio, Alvaro
Fananas-Mastral, Martin
ORGANIC LETTERS, 2022, 24 (37) : 6874 - 6879

← 1 2 3 4 5 →