A Metal-Organic Framework/DNA Hybrid System as a Novel Fluorescent Biosensor for Mercury(II) Ion Detection

被引:149
|
作者
Wu, Lan-Lan [1 ,2 ]
Wang, Zhuo [1 ,2 ]
Zhao, Shu-Na [1 ,2 ]
Meng, Xing [1 ,2 ]
Song, Xue-Zhi [3 ]
Feng, Jing [1 ]
Song, Shu-Yan [1 ]
Zhang, Hong-Jie [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, 5625 Renmin St, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Dalian Univ Technol, Sch Petr & Chem Engn, 2 Dagong Rd, Panjin 124221, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
DNA; fluorescence; host-guest systems; mercury; metal-organic frameworks; QUANTUM DOTS; SELECTIVE DETECTION; SENSING PLATFORM; BASE-PAIRS; DNA; HG2+; NANOPARTICLES; DELIVERY; REMOVAL; SENSOR;
D O I
10.1002/chem.201503335
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mercury(II) ions have emerged as a widespread environmental hazard in recent decades. Despite different kinds of detection methods reported to sense Hg2+, it still remains a challenging task to develop new sensing molecules to replenish the fluorescence-based apparatus for Hg2+ detection. This communication demonstrates a novel fluorescent sensor using UiO-66-NH2 and a T-rich FAM-labeled ssDNA as a hybrid system to detect Hg2+ sensitively and selectively. To the best of our knowledge, it has rarely been reported that a MOF is utilized as the bio-sensing platform for Hg2+ assay.
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页码:477 / 480
页数:4
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