Copper-Catalyzed Tandem Sulfuration/Annulation of Propargylamines with Sulfur via C-N Bond Cleavage

被引：23
|
作者：
Xu, Hong-Hui [1 ]
Zhang, Xiao-Hong [1 ]
Zhang, Xing-Guo [1 ,2 ]
机构：
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
[2] Hezhou Univ, Guangxi Key Lab Calcium Carbonate Resources Compr, Hezhou 542899, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 84卷 / 12期
基金：
中国国家自然科学基金;
关键词：
INTRAMOLECULAR CHARGE-TRANSFER; TERTIARY-AMINES; PHOSPHORUS PENTASULFIDE; REAGENT COMBINATION; ARYL IODIDES; DERIVATIVES; EFFICIENT; ESTERS; DONOR; 1,2-DITHIOLE-3-THIONES;
D O I：
10.1021/acs.joc.9b00685
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper-catalyzed aerobic oxidative sulfuration and annulation of propargylamines with elemental sulfur is described. The tandem reaction involves C-N bond cleavage and the formation of multiple C-S bonds, affording 1,2-dithiole-3-thiones in good to excellent yields with good functional group tolerance.
引用
收藏
页码：7894 / 7900
页数：7
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