Synthesis of sulfonamides via copper-catalyzed oxidative C-N bond cleavage of tertiary amines

被引：26
|
作者：
Ji, Jing
Liu, Zhengyi
Liu, Ping
Sun, Peipei [1 ]
机构：
[1] Nanjing Normal Univ, Coll Chem & Mat Sci, Nanjing 210023, Jiangsu, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 29期
基金：
中国国家自然科学基金;
关键词：
SULFUR-DIOXIDE; DIRECT ACCESS; ARYL; AMIDATION; ACTIVATIONS; AMINOLYSIS; ANTICANCER; POTENT; DABSO; ACIDS;
D O I：
10.1039/c6ob01208f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A copper-catalyzed coupling reaction of sulfonyl chlorides with tertiary amines via the oxidative C-N bond cleavage of tertiary amines was developed. Sulfonamides were synthesized using this strategy in moderate to good yields. The reaction was applicable to various tertiary amines, as well as sulfonyl chlorides.
引用
收藏
页码：7018 / 7023
页数：6
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