Synthesis, Structural Characterization, Spectroscopic Properties of Copper (I) Complexes [Cu2(CH3CN)4(dppm)2](BF4)2 and [Cu2(pmk)(dppm)2](BF4)2 (dppm = bis(diphenylphosphino)methane, pmk = bis(2-pyridylmethyl) ketazine)

被引：4

作者：

Huang, Ting-Hong ^{[1
]}

Zhang, Min-Hua ^{[1
]}

Tao, Min-Li ^{[1
]}

Wang, Xiu-Jian ^{[2
]}

机构：

[1] Tianjin Univ, R&D Ctr Petrochem Technol, Key Lab Green Chem Technol, Minist Educ China, Tianjin 300072, Peoples R China

[2] Guangxi Normal Univ, Sch Chem & Chem Engn, Key Lab Chem & Mol Engn Med Resources, Minist Educ China, Guilin, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2014年 / 44卷 / 07期

关键词：

copper(I) complexes; crystal structures; spectrum; CU(I) PHENANTHROLINE COMPLEX; LIGANDS; DIPHOSPHINE; DIFFRACTION; CRYSTALS; POLYMERS;

D O I：

10.1080/15533174.2013.797442

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new binuclear copper(I) complexes, [Cu-2(CH3CN)(4) (dppm)(2)](BF4)(2) (1), [Cu-2(pmk)(dppm)(2)](BF4)(2) (2) (dppm = bis(diphenylphosphino)methane, pmk = bis(2-pyridylmethyl) ketazine), were designed and synthesized. These complexes were characterized by IR, H-1-NMR, P-31-NMR, UV-vis spectrum, and X-ray crystal structure analysis. The structural analysis reveal each copper(I) in the complexes is four coordinate N2P2 and adopts a distorted-tetrahedral geometry. At room temperature, all the complexes exhibit middle or weak photoluminescence in the solid state (485-504nm) or acetonitrile solution (380-585nm).

引用

页码：986 / 990

页数：5

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