Synthesis, Structural Characterization, Spectroscopic Properties of Copper (I) Complexes [Cu2(CH3CN)4(dppm)2](BF4)2 and [Cu2(pmk)(dppm)2](BF4)2 (dppm = bis(diphenylphosphino)methane, pmk = bis(2-pyridylmethyl) ketazine)

被引:4
|
作者
Huang, Ting-Hong [1 ]
Zhang, Min-Hua [1 ]
Tao, Min-Li [1 ]
Wang, Xiu-Jian [2 ]
机构
[1] Tianjin Univ, R&D Ctr Petrochem Technol, Key Lab Green Chem Technol, Minist Educ China, Tianjin 300072, Peoples R China
[2] Guangxi Normal Univ, Sch Chem & Chem Engn, Key Lab Chem & Mol Engn Med Resources, Minist Educ China, Guilin, Peoples R China
关键词
copper(I) complexes; crystal structures; spectrum; CU(I) PHENANTHROLINE COMPLEX; LIGANDS; DIPHOSPHINE; DIFFRACTION; CRYSTALS; POLYMERS;
D O I
10.1080/15533174.2013.797442
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new binuclear copper(I) complexes, [Cu-2(CH3CN)(4) (dppm)(2)](BF4)(2) (1), [Cu-2(pmk)(dppm)(2)](BF4)(2) (2) (dppm = bis(diphenylphosphino)methane, pmk = bis(2-pyridylmethyl) ketazine), were designed and synthesized. These complexes were characterized by IR, H-1-NMR, P-31-NMR, UV-vis spectrum, and X-ray crystal structure analysis. The structural analysis reveal each copper(I) in the complexes is four coordinate N2P2 and adopts a distorted-tetrahedral geometry. At room temperature, all the complexes exhibit middle or weak photoluminescence in the solid state (485-504nm) or acetonitrile solution (380-585nm).
引用
收藏
页码:986 / 990
页数:5
相关论文
共 50 条
  • [31] SUBSTITUTIONS INVOLVING [RH2(O2CME)2(CH3CN)4]2+[BF4]2
    CHISHOLM, MH
    IYER, S
    HUFFMAN, JC
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 205 - INOR
  • [32] Properties of [Pd2X2(dppm)2] (X=Cl, SnCl3, dppm = bis(diphenylphosphino)methane) complexes on porous Vycor glass
    Gimenez, ID
    Alves, OL
    [J]. JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2004, 15 (05) : 640 - 645
  • [33] Synthesis, HSA-Binding and Anticancer Properties of [Cu2(μ-dppm)2(N∧N)2]2+
    Babgi, Bandar A.
    Alzaidi, Najah A.
    Alsayari, Jalal H.
    Emwas, Abdul-Hamid M.
    Jaremko, Mariusz
    Abdellattif, Magda H.
    Aljandali, Mutlaq
    Hussien, Mostafa A.
    [J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2022, 32 (10) : 4005 - 4013
  • [34] BONDING PROPERTIES OF CU(II)-N CHROMOPHORES - PREPARATION, STRUCTURE AND SPECTROSCOPIC PROPERTIES OF MIXED-LIGAND 2,2'/6',2''-TERPYRIDINE COPPER(II) COMPLEXES - MOLECULAR-STRUCTURES OF [CU(TERPYRIDINE)(4-METHYLIMIDAZOLE)(H2O)(BF4)] (BF4) AND [CU(TERPYRIDINE)(3-METHYLPYRIDINE)(BF4)2]
    SU, CC
    LI, CB
    [J]. POLYHEDRON, 1994, 13 (05) : 825 - 834
  • [35] Synthesis of [Au3Fe2(CO)(8)(dppm)](-) and [Au5Fe2(CO)(8)(dppm)(2)](+): X-ray structures of [NEt(4)][Au3Fe2(CO)(8)(dppm)] and [Au5Fe2(CO)(8)(dppm)(2)][BF4]
    Albano, VG
    Iapalucci, MC
    Longoni, G
    Manzi, L
    Monari, M
    [J]. ORGANOMETALLICS, 1997, 16 (04) : 497 - 499
  • [36] COPPER(II) AND COPPER(I) COMPLEXES STABILIZED BY PHOSPHINE OXIDES - SYNTHESIS AND CHARACTERIZATION OF THE CATIONIC COMPLEXES [CU(ODPPF)(2)(ETOH)](2+) AND [CU(ODPPF)(2)](2+), PRECURSORS OF THE NOVEL COPPER(I) ADDUCT [CU(ODPPF)(2)](+) (ODPPF=1,1'-BIS(OXODIPHENYLPHOSPHORANYL)FERROCENE) - CRYSTAL-STRUCTURE OF [CU(ODPPF)(2)(ETOH)](BF4)(2) AND [CU(ODPPF)(2)](BF4)(2)
    PILLONI, G
    VALLE, G
    CORVAJA, C
    LONGATO, B
    CORAIN, B
    [J]. INORGANIC CHEMISTRY, 1995, 34 (23) : 5910 - 5918
  • [37] Luminescent PtII-MI (M = Cu, Ag, Au) heteronuclear alkynyl complexes prepared by reaction of [Pt(CCR)4]2- with [M2(dppm)2]2+ (dppm = bis(diphenylphosphino)methane)
    Yin, GQ
    Wei, QH
    Zhang, LY
    Chen, ZN
    [J]. ORGANOMETALLICS, 2006, 25 (03) : 580 - 587
  • [38] Solution-State Spin Crossover in a Family of [Fe(L)2(CH3CN)2](BF4)2 Complexes
    Wilson, Benjamin H.
    Scott, Hayley S.
    Archer, Rosanna J.
    Mathoniere, Corine
    Clerac, Rodolphe
    Kruger, Paul E.
    [J]. MAGNETOCHEMISTRY, 2019, 5 (02)
  • [39] SYNTHESIS AND CHARACTERIZATION OF WATER-SOLUBLE [PD(TRIPHOSPHINE)(CH3CN)](BF4)(2) COMPLEXES FOR CO2 REDUCTION
    HERRING, AM
    STEFFEY, BD
    MIEDANER, A
    WANDER, SA
    DUBOIS, DL
    [J]. INORGANIC CHEMISTRY, 1995, 34 (05) : 1100 - 1109
  • [40] Synthesis and Characterization of Water-Soluble [Pd(triphosphine)(CH3CN)](BF4)2 Complexes for CO2 Reduction
    Herring, A. M.
    Steffey, B. D.
    Miedaner, A.
    Wander, S. A.
    [J]. Inorganic Chemistry, 34 (05):