Synthesis, Structural Characterization, Spectroscopic Properties of Copper (I) Complexes [Cu2(CH3CN)4(dppm)2](BF4)2 and [Cu2(pmk)(dppm)2](BF4)2 (dppm = bis(diphenylphosphino)methane, pmk = bis(2-pyridylmethyl) ketazine)

被引：4
|
作者：
Huang, Ting-Hong [1 ]
Zhang, Min-Hua [1 ]
Tao, Min-Li [1 ]
Wang, Xiu-Jian [2 ]
机构：
[1] Tianjin Univ, R&D Ctr Petrochem Technol, Key Lab Green Chem Technol, Minist Educ China, Tianjin 300072, Peoples R China
[2] Guangxi Normal Univ, Sch Chem & Chem Engn, Key Lab Chem & Mol Engn Med Resources, Minist Educ China, Guilin, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2014年 / 44卷 / 07期
关键词：
copper(I) complexes; crystal structures; spectrum; CU(I) PHENANTHROLINE COMPLEX; LIGANDS; DIPHOSPHINE; DIFFRACTION; CRYSTALS; POLYMERS;
D O I：
10.1080/15533174.2013.797442
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new binuclear copper(I) complexes, [Cu-2(CH3CN)(4) (dppm)(2)](BF4)(2) (1), [Cu-2(pmk)(dppm)(2)](BF4)(2) (2) (dppm = bis(diphenylphosphino)methane, pmk = bis(2-pyridylmethyl) ketazine), were designed and synthesized. These complexes were characterized by IR, H-1-NMR, P-31-NMR, UV-vis spectrum, and X-ray crystal structure analysis. The structural analysis reveal each copper(I) in the complexes is four coordinate N2P2 and adopts a distorted-tetrahedral geometry. At room temperature, all the complexes exhibit middle or weak photoluminescence in the solid state (485-504nm) or acetonitrile solution (380-585nm).
引用
收藏
页码：986 / 990
页数：5
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