[η2-8-(tert-butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV)

被引：1

作者：

Kooijman, Huub

van Leijen, Monique M.

Akkerman, Otto S.

Bickelhaupt, Friedrich

Spek, Anthony L.

机构：

[1] Univ Utrecht, Bijvoet Ctr Biomol Res, Dept Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

[2] Vrije Univ Amsterdam, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806021726

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ti(C5H5)(2)(C15H15N)], displays an iminoacyl fragment in an N-outside conformation, indicating that the C = N vector points away from the sigma-bonded C atom. Considering only the geometrical centres of all eta = coordinated groups, the Ti-IV ion adopts a severely distorted tetrahedral configuration. The crystal packing displays a short C - H center dot center dot center dot pi contact linking the molecules into an infinite chain running along the b-axis direction.

引用

页码：M1545 / M1547

页数：3

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