[η2-8-(tert-butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV)

被引：1
|
作者：
Kooijman, Huub
van Leijen, Monique M.
Akkerman, Otto S.
Bickelhaupt, Friedrich
Spek, Anthony L.
机构：
[1] Univ Utrecht, Bijvoet Ctr Biomol Res, Dept Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands
[2] Vrije Univ Amsterdam, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806021726
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ti(C5H5)(2)(C15H15N)], displays an iminoacyl fragment in an N-outside conformation, indicating that the C = N vector points away from the sigma-bonded C atom. Considering only the geometrical centres of all eta = coordinated groups, the Ti-IV ion adopts a severely distorted tetrahedral configuration. The crystal packing displays a short C - H center dot center dot center dot pi contact linking the molecules into an infinite chain running along the b-axis direction.
引用
收藏
页码：M1545 / M1547
页数：3
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