Rhodium-catalyzed Electrophilic Amination of Arylboronic Acids with Secondary Hydroxylamines

被引：13

作者：

Yasuhisa, Tomohiro ^{[1
]}

Hirano, Koji ^{[1
]}

Miura, Masahiro ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY LETTERS | 2017年 / 46卷 / 04期

关键词：

Arylamine; Electrophilic amination; Rhodium catalyst; HETEROARENES; AMIDATION; ALKYL;

D O I：

10.1246/cl.161158

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rhodium(III)-catalyzed electrophilic amination of arylboronic acids with secondary hydroxylamines has been developed. The rhodium catalysis is compatible with heteroarylboronic acids as well as acyl and alkoxycarbonyl protecting groups on the nitrogen of O-acylhydroxylamines, and the corresponding secondary anilines are obtained in good to excellent yields.

引用

页码：463 / 465

页数：3

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