Highly enantioselective rhodium-catalyzed conjugate addition of arylboronic acids to enones at room temperature

被引：27
|
作者：
Martina, SLX [1 ]
Minnaard, AJ [1 ]
Hessen, B [1 ]
Feringa, BL [1 ]
机构：
[1] Univ Groningen, Stratingh Inst, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 42期
关键词：
asymmetric 1,4-addition; arylboronic acid; rhodium-catalysis; phosphoramidite;
D O I：
10.1016/j.tetlet.2005.08.095
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The rhodium-phosphoramidite-catalyzed asymmetric conjugate addition of arylboronic acids to enones proceeds at room temperature using [Rh(OH)(cod)](2) or [RhCl(cod)](2)/KOH as stable and readily available catalyst precursors. (c) 2005 Published by Elsevier Ltd.
引用
收藏
页码：7159 / 7163
页数：5
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