Synthesis of Chiral Cyclic Carbonates via Kinetic Resolution of Racemic Epoxides and Carbon Dioxide

被引：25

作者：

Wu, Xiao ^{[1
]}

Castro-Osma, Jose A. ^{[2
]}

North, Michael ^{[1
]}

机构：

[1] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England

[2] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Ctr Innovac Quim Avanzada ORFEO CINQA, Inst Reg Invest Cient Aplicada, E-13071 Ciudad Real, Spain

来源：

SYMMETRY-BASEL | 2016年 / 8卷 / 01期

关键词：

carbon dioxide; catalysis; metal catalysts; cyclic carbonates; kinetic resolution; ASYMMETRIC CYCLOADDITION; PROPYLENE-OXIDE; CO2; CATALYSIS; COMPLEXES;

D O I：

10.3390/sym8010004

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The catalytic synthesis of cyclic carbonates using carbon dioxide as a C1-building block is a highly active area of research. Here, we review the catalytic production of enantiomerically enriched cyclic carbonates via kinetic resolution of racemic epoxides catalysed by metal-containing catalyst systems.

引用

页数：6

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