Efficient catalytic synthesis of optically active cyclic carbonates via coupling reaction of epoxides and carbon dioxide

被引：66
|
作者：
Chen, Shu-Wei [1 ]
Kawthekar, Rahul B. [1 ]
Kim, Geon-Joong [1 ]
机构：
[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 02期
关键词：
chiral cobalt salen; epoxides; Lewis acid; resolution;
D O I：
10.1016/j.tetlet.2006.11.014
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral Co(salen) complexes bearing the Lewis acid of group 13 can efficiently catalyze the reactions of carbon dioxide with epoxides in the presence of catalytic amounts of alkali metal salts, quaternary ammonium halide or ionic liquids. They exhibited excellent activity for producing enantiomerically enriched cyclic carbonates. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：297 / 300
页数：4
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