Odorless, Transition-Metal-Free N-Sulfenylation of Sulfoximines with Thiosulfonates under Mild Conditions

被引：3

作者：

Kang, Xiaokang ^{[1
]}

Wang, Helin ^{[1
]}

Zeng, Qingle ^{[1
]}

机构：

[1] Chengdu Univ Technol, Coll Mat Chem & Chem Engn, State Key Lab Geohazard Prevent & Geoenvironm Prot, Chengdu 610059, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 47期

关键词：

Organosulfur chemistry; N-Sulfenyl sulfoximines; N-Sulfenylation; Sulfoximines; Thiosulfonates; ASYMMETRIC-SYNTHESIS; BOND FORMATION; C-S; BIOLOGICAL-ACTIVITIES; EFFICIENT SYNTHESIS; DESIGN; DERIVATIVES; POTENT; CYCLIZATION; ARYLATIONS;

D O I：

10.1002/ejoc.202201229

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Sulfenylation of sulfoximines with thiosulfonates under mild conditions was disclosed. By our method, a series of aliphatic and aromatic N-sulfenyl sulfoximines were synthesized with good to excellent yields in the absence of transition metals. The applicability of this method was demonstrated by gram scale experiments.

引用

页数：4

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