Odorless, Transition-Metal-Free N-Sulfenylation of Sulfoximines with Thiosulfonates under Mild Conditions

被引：3
|
作者：
Kang, Xiaokang [1 ]
Wang, Helin [1 ]
Zeng, Qingle [1 ]
机构：
[1] Chengdu Univ Technol, Coll Mat Chem & Chem Engn, State Key Lab Geohazard Prevent & Geoenvironm Prot, Chengdu 610059, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 47期
关键词：
Organosulfur chemistry; N-Sulfenyl sulfoximines; N-Sulfenylation; Sulfoximines; Thiosulfonates; ASYMMETRIC-SYNTHESIS; BOND FORMATION; C-S; BIOLOGICAL-ACTIVITIES; EFFICIENT SYNTHESIS; DESIGN; DERIVATIVES; POTENT; CYCLIZATION; ARYLATIONS;
D O I：
10.1002/ejoc.202201229
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N-Sulfenylation of sulfoximines with thiosulfonates under mild conditions was disclosed. By our method, a series of aliphatic and aromatic N-sulfenyl sulfoximines were synthesized with good to excellent yields in the absence of transition metals. The applicability of this method was demonstrated by gram scale experiments.
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页数：4
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