Solvent-induced single-crystal to single-crystal transformation of a Zn4O-containing doubly interpenetrated metal-organic framework with a pcu net

被引：19

作者：

Lee, Jae Hwa ^{[1
]}

Kim, Tae Kyung ^{[1
]}

Suh, Myunghyun Paik ^{[2
]}

Moon, Hoi Ri ^{[1
]}

机构：

[1] Ulsan Natl Inst Sci & Technol, Dept Chem, Ulsan 689798, South Korea

[2] Hanyang Univ, Dept Chem, Seoul 133791, South Korea

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 46期

基金：

新加坡国家研究基金会;

关键词：

GAS-SORPTION PROPERTIES; BILAYER OPEN FRAMEWORK; PI-PI-INTERACTIONS; GUEST EXCHANGE; COORDINATION POLYMER; TEMPERATURE; DYNAMICS; REMOVAL; BINDING; SITES;

D O I：

10.1039/c5ce01074h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Guest molecules in a metal-organic framework (MOF), [Zn4O(CPMA)(3)]center dot 6DMF (DMF = N, N-dimethylformamide), with an interpenetrating pcu net were exchanged with benzene, n-hexane, and methanol in a single-crystal to single-crystal (SC-SC) manner, which involved the sliding motion of the interpenetrating network, as well as the dynamic movements of the molecular components, and was triggered by host-guest interactions.

引用

页码：8807 / 8811

页数：5

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