A Cuprous [4 x 4] Grid: Single-Crystal to Single-Crystal Transformation and Fading of Luminescence by Solvent Inclusion

被引：12
|
作者：
Yu, Fei [1 ]
Li, Jia-Qian [1 ]
Kurmoo, Mohamedally [2 ]
Zuo, Jing-Lin [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Adv Microstruct, State Key Lab Coordinat Chem, Nanjing 210023, Jiangsu, Peoples R China
[2] Univ Strasbourg, Inst Chim Strasbourg, CNRS UMR 7177, 4 Rue Blaise Pascal, F-67008 Strasbourg, France
来源：
INORGANIC CHEMISTRY | 2018年 / 57卷 / 24期
基金：
中国国家自然科学基金;
关键词：
COMPLEXES; COUNTERANIONS; FUNCTIONALIZATION; EXCHANGE; CU; NI;
D O I：
10.1021/acs.inorgchem.8b02878
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The subtle balance of the metrics of the highly supple 5,5'-pyridyl-3,3'-bis-1H-pyrazolate and the variable coordination numbers of Cu(I) favor the stabilization of a [4 X 4] grid complex with all Cu(I). It has numerous cuprophilic bonds (Cu center dot center dot center dot Cu = 2.56-3.02 angstrom), and consequently, exhibits strong orange luminescence that fades upon insertion of solvents without loss of crystallinity.
引用
收藏
页码：15040 / 15043
页数：4
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