Nucleophilic additions of the cyanide anion to 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene

被引：0

作者：

Jacquot-Rousseau, S

Schmitt, G

Laude, B

Kubicki, MM

Blacque, O

机构：

[1] Univ Franche Comte, Lab Chim Mat & INterfaces Pole Mat Mol, F-25030 Besancon, France

[2] Univ Bourgogne, Lab Synth & Electrosynth Organomet, UMR 5632, F-21000 Dijon, France

来源：

JOURNAL OF CHEMICAL RESEARCH | 2002年 / 04期

关键词：

potassium cyanide; 4,4-dichloro; 1,1-diphenyl-2-azabuta-1,3-diene;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unexpected formation of a 2H-pyrrole by reaction of potassium cyanide with 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene and the mechanism of this reaction are described and the structures of the product and a trapped intermediate confirmed by X-ray crystallographic studies.

引用

页码：151 / 152

页数：2

共 39 条

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[33] MODEL REACTIONS FOR STERICALLY CONTROLLED SYNTHESES OF CYCLOHEX-2-ENONES WITH 4,4-QUATERNARY OR 5,5-QUATERNARY CENTERS - A DIRECT CHIRAL SYNTHESIS OF 4-ALLYL-4-CYANOCYCLOHEX-2-ENONE FROM THE ANION OF (+)-TRICARBONYL(5-CYANO-2-METHOXYCYCLOHEXA-1,3-DIENE)IRON
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[34] PHASE-TRANSFER-CATALYZED ADDITIONS .12. PREPARATION AND STEREOCHEMISTRY OF 4-ARYL-3-CYANO-1,1-DIPHENYL-2-AXABUTA-1,3-DIENES
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[35] Optical resolution, configurational stability, and coordination chemistry of the P-chiral heterocyclic diphosphine 1,1′-diphenyl-3,3′,4,4′-tetramethyl-2,2′-diphosphole-3,3′-diene
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[36] 1′,3′,4′,5′,7′,8′-Hexafluoro-1,1",2,2",3,3",4,4"-octaphenyl-2′,6′-dihydrodispiro[cyclopenta-1,3-diene-5,2′-naphthalene-6′,5"-cyclopenta-1",3"-diene] dichloromethane monosolvate
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[37] Alkylation of 2-butyl-4,4-dimethyl-4H-benzo[d][1,3]-oxathiine-1,1-dioxide, a new class of acyl anion equivalents as an alternative to dithianes
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[38] REACTION OF 1,3-DI-TERT-BUTYL-2,2-DIMETHYL-4,4-DICHLORO-1,3,2,4-LAMBDA-4-DIAZASILASTANNETIDINE WITH SILVER TRIFLUOROMETHANESULFONATE - THE CRYSTAL-STRUCTURE OF POLYMERIC 1,3-DI-TERT-BUTYL-2,4-DIMETHYL-2,4-DITRIFLUOROMETHANESULFONATE-1,3,2,4-LAMBDA-5-DIAZASILASTANNETIDINE
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[39] REACTIONS OF COORDINATED LIGANDS .16. OXIDATIVE-ADDITION OF HEXAFLUOROBUT-2-YNE AND 3,3,3-TRIFLUOROPROP-1-YNE TO TRICARBONYL(1,3-DIENE)-IRON AND RUTHENIUM AND TRICARBONYL(DIPHENYL-O-STYRYLPHOSPHINE)-IRON COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF [RU(CO)2(P(OCH2)3-CME)(C6H8)(C4F6)2]C
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