Nucleophilic additions of the cyanide anion to 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene

被引：0

作者：

Jacquot-Rousseau, S

Schmitt, G

Laude, B

Kubicki, MM

Blacque, O

机构：

[1] Univ Franche Comte, Lab Chim Mat & INterfaces Pole Mat Mol, F-25030 Besancon, France

[2] Univ Bourgogne, Lab Synth & Electrosynth Organomet, UMR 5632, F-21000 Dijon, France

来源：

JOURNAL OF CHEMICAL RESEARCH | 2002年 / 04期

关键词：

potassium cyanide; 4,4-dichloro; 1,1-diphenyl-2-azabuta-1,3-diene;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unexpected formation of a 2H-pyrrole by reaction of potassium cyanide with 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene and the mechanism of this reaction are described and the structures of the product and a trapped intermediate confirmed by X-ray crystallographic studies.

引用

页码：151 / 152

页数：2

共 39 条

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[22] The hetero Diels-Alder reaction featuring 2-phenyl-4-dimethylamino-1-thia-3-azabuta-1,3-diene as diene component:: a clear example of a thermodynamically-controlled process
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[24] Tricarbonyl[(1-4-η)-2-methoxy-5-methylenecyclohexa-1, 3-diene]iron as a synthetic intermediate: sequential electrophilic and nucleophilic additions
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[26] 1,1-DIFLUORO-2-TRIPHENYLSILOXYBUTA-1,3-DIENE AS A POTENTIALLY USEFUL FLUORINE-CONTAINING BUILDING BLOCK - PREPARATION AND [4+2] AND [2+2] CYCLOADDITIONS
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[27] CONVERSION OF 2,5-DIHYDROTHIOPHENE 1,1-DIOXIDES INTO HIGHLY FUNCTIONALIZED (ETA-4-BUTA-1,3-DIENE)TRICARBONYLIRON(0) COMPLEXES
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[30] The crystal structure of 4,4' -dichloro-3,5'-diphenyl-1'H-1,3' - bipyrazole, C18H12Cl2N4
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