Metal-organic frameworks based on [Re6Se8(CN)6]4-cluster anions, Yb3+cations, and thiophene-2,5-dicarboxylate linkers

被引：5
|
作者：
Litvinova, Y. M. [1 ]
Gayfulin, Y. M. [1 ]
Samsonenko, D. G. [1 ,2 ]
Mironov, Y. V. [2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, 3 Prosp Akad Lavrentieva, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, 2 Ul Pirogova, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2020年 / 69卷 / 07期
基金：
俄罗斯基础研究基金会;
关键词：
rhenium; cluster complex; lanthanides; crystal structure; metal-organic frameworks; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; LANTHANIDE; COMPLEXES; LUMINESCENT; CONVERSION; CLUSTER; NANOPARTICLES;
D O I：
10.1007/s11172-020-2896-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of [Re6Se8(CN)(6)](4-)cluster anions with Ln(3+)cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)(3)}(2)(tdc)-Re6Se8(CN)(6)]center dot 10H(2)O(1)and CsK0,5[{Yb-4(OH)(4)(H2O)(7,5)(NO3)(0,5)(tdc)(2)}{Re6Se8(CN)(6)}]NO3 center dot 16.5H(2)O(2)(tdc is the thiophene-2,5-dicarboxylate anion). Compound1crystallizes in a wide pH range (3.0-6.5) and has a porous structure with large open voids accessible to guest molecules. Compound2crystallizes at pH 6.0-6.5, contains polynuclear cationic complexes [Yb-4(OH)(4)](8+), and also has a framework structure.
引用
收藏
页码：1264 / 1271
页数：8
相关论文
共 38 条
  • [1] Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers
    Y. M. Litvinova
    Y. M. Gayfulin
    D. G. Samsonenko
    Y. V. Mironov
    [J]. Russian Chemical Bulletin, 2020, 69 : 1264 - 1271
  • [2] SYNTHESIS AND STRUCTURE OF TWO NOVEL METAL-ORGANIC FRAMEWORKS BASED ON CLUSTER ANIONS [Re6Se8(CN)6]4–, CATIONS Tb3+, AND ISONICOTINATE ANIONS
    Yu. M. Litvinova
    Ya. M. Gayfulin
    D. G. Samsonenko
    P. V. Dorovatovsky
    V. A. Lazarenko
    Yu. V. Mironov
    [J]. Journal of Structural Chemistry, 2020, 61 : 1630 - 1638
  • [3] SYNTHESIS AND STRUCTURE OF TWO NOVEL METAL-ORGANIC FRAMEWORKS BASED ON CLUSTER ANIONS [Re6Se8(CN)6]4-, CATIONS Tb3+, AND ISONICOTINATE ANIONS
    Litvinova, Yu M.
    Gayfulin, Ya M.
    Samsonenko, D. G.
    Dorovatovsky, P., V
    Lazarenko, V. A.
    Mironov, Yu, V
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 61 (10) : 1630 - 1638
  • [4] Effect of Lanthanide Contraction on Crystal Structures of Three-Dimensional Lanthanide Based Metal-Organic Frameworks with Thiophene-2,5-Dicarboxylate and Oxalate
    Xu, Jing
    Cheng, Jianwen
    Su, Weiping
    Hong, Maochun
    [J]. CRYSTAL GROWTH & DESIGN, 2011, 11 (06) : 2294 - 2301
  • [5] New coordination polymers based on paramagnetic cluster anions [Re6Se8(CN)6]3− and rare earth cations: The synthesis and structure of [{Ln(H2O)3)}{Re6Se8(CN)6}]·3.5H2O
    M. S. Tarasenko
    N. G. Naumov
    A. V. Virovets
    D. Yu. Naumov
    N. V. Kuratieva
    Yu. V. Mironov
    V. N. Ikorskii
    V. E. Fedorov
    [J]. Journal of Structural Chemistry, 2005, 46 : S137 - S144
  • [6] New coordination polymers based on paramagnetic cluster anions [Re6Se8(Cn)6]3- and rare earth cations:: The synthesis and structure of [{Ln(H2O)3)}{Re6Se8(CN)6}]•3.5H2O
    Tarasenko, M. S.
    Naumov, N. G.
    Virovets, A. V.
    Naumov, D. Yu.
    Kuratieva, N. V.
    Mironov, Yu. V.
    Ikorskii, V. N.
    Fedorov, V. E.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (Suppl 1) : S137 - S144
  • [7] COORDINATION POLYMERS BASED ON [Re6Se8(CN)6]4- CLUSTER ANION, LANTHANIDE CATIONS, AND TETRAATOMIC ALCOHOL ERYTHRITOL
    Tarasenko, M. S.
    Ledneva, A. Yu.
    Naumov, D. Yu.
    Naumov, N. G.
    Fedorov, V. E.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (01) : 172 - 179
  • [8] Coordination polymers based on [Re6Se8(CN) 6]4- cluster anion, lanthanide cations, and tetraatomic alcohol erythritol
    Tarasenko M.S.
    Ledneva A.Yu.
    Naumov D.Yu.
    Naumov N.G.
    Fedorov V.E.
    [J]. Journal of Structural Chemistry, 2011, 52 (1) : 172 - 179
  • [9] Structure and catalytic activity of a hexarhenium cluster-supported copper cubanes [{Cu4(μ-OH)4(NH3)7}2{Re6Se8(CN)6}][Re6Se8(CN)6]•2H2O
    Xu, Li
    Kim, Youngmee
    Kim, Sung-Jin
    Kim, Hee Jin
    Kim, Cheal
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (05) : 586 - 589
  • [10] Coordination polymers based on rhenium octahedral chalcocyanide cluster [Re6Se8(CN)6]4- and lanthanide ions solvated with dimethylformamide
    Litvinova, Yulia M.
    Gayfulin, Yakov M.
    Samsonenko, Denis G.
    Dorovatovskiy, Pavel, V
    Lazarenko, Vladimir A.
    Brylev, Konstantin A.
    Mironov, Yuri, V
    [J]. INORGANICA CHIMICA ACTA, 2021, 528
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