Effect of Sb2O3 on Thermal Properties of Glasses in Bi2O3-B2O3-SiO2 System

被引：33
|
作者：
Zhang, Yaping [1 ]
Yang, Yunxia [1 ]
Ou, Yuwen [1 ]
Hua, Wei [1 ]
Zheng, Jiahua [1 ]
Chen, Guorong [1 ]
机构：
[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Ultrafine Mat, Minist Educ, Shanghai 200237, Peoples R China
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2009年 / 92卷 / 08期
关键词：
BISMUTH BORATE; OPTICAL-PROPERTIES;
D O I：
10.1111/j.1551-2916.2009.03127.x
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Glasses with compositions 50Bi(2)O(3)-xSb(2)O(3)-10B(2)O(3)-(40-x) SiO2 (x=0, 1, 3, 5, 8, 10) have been prepared by conventional melt quench technique. Substitution of Sb2O3 for SiO2 exerted an obvious effect on properties of glasses, especially, increased glass transition temperature (T-g) and crystalline temperature (T-c) greatly. Results of infrared transmission spectra attributed the effect to the formation of new bridging bonds of Sb-O-B and Sb-O-Si in glass network.
引用
收藏
页码：1881 / 1883
页数：3
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