The synthesis and characterization of a new layered chlorozincophosphate Zn(HPO4)Cl[C4H10N]

被引：1
|
作者：
Kefi, R.
Ben Nasr, C. [1 ]
Lefebvre, F.
Rzaigui, M.
机构：
[1] Fac Sci Bizerte, Lab Chim Mat, Zarzouna 7021, Tunisia
[2] Ecole Super Chim Phys Elect, Lab Chim Organomet Surface, Villeurbanne, France
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2006年 / 181卷 / 10期
关键词：
layered compounds; NMR spectroscopy; pyrrolidine (organic template); X-ray diffraction;
D O I：
10.1080/10426500600614782
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Along a systematic study of open-framework materials aiming at producing new molecular sieves, we characterized a new zincophosphate Zn(HPO4)Cl[C4H10N]. It was synthesized under mild conditions (r.t.) in the presence of pyrrolidinium as an organic-structure directing agent. The structure of this compound, determinated by single crystal X-ray diffraction, consists of anionic parallel [Zn(HPO4)Cl]sheets alternating with thick slabs of organic molecules (C4H10N)(+). These latters are linked to the anionic sheets through hydrogen bonds. Zn(HPO4) Cl[C4H10N] crystallizes in the monoclinic system and the space group C2/c (No. 9) with cell parameters a = 24,83(9), b = 9,258(5), c = 8.778(3), beta = 110,45(4), Z = 8, V = 1891.0(14) angstrom(3), R = 0.045, and R-w = 0.07. Solid state P-31 and C-13 MAS NMR spectroscopies are in agreement with the X-ray structure.
引用
收藏
页码：2231 / 2246
页数：16
相关论文
共 50 条
  • [1] Synthesis and characterization of a layered chlorozincophosphate Zn(HPO4)Cl•C4H10NO]
    Kefi, R.
    Rayes, A.
    Ben Nasr, C.
    Rzaigui, M.
    [J]. MATERIALS RESEARCH BULLETIN, 2007, 42 (02) : 288 - 298
  • [2] Synthesis and structural characterization of a new layered chlorozincophosphate, Zn(HPO4)Cl•[H3N(CH2)6NH3]0.5
    Rayes, A
    Ben Nasr, C
    Rzaigui, A
    [J]. MATERIALS RESEARCH BULLETIN, 2004, 39 (4-5) : 571 - 580
  • [3] Synthesis and characterization of a new chlorozincophosphate [H3N(CH2)2NH3]0.5Zn(HPO4)Cl
    Rayes, A
    Ben Nasr, C
    Rzaigui, M
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2005, 180 (01) : 41 - 52
  • [4] Synthesis and characterization of a new layered zinc phosphate:: (C3H4N2)3Zn4(HPO4)(PO4)2 with imidazole coordinating to Zn atoms
    Cui, AL
    Yao, YW
    [J]. CHEMISTRY LETTERS, 2001, (11) : 1148 - 1149
  • [5] Hydrothermal synthesis and characterization of a new organic templated metallophosphate [Zn(H2PO4)2(HPO4)][C7H17N2]
    Kefi, R.
    Ben Nasr, C.
    Lefebvre, F.
    Rzaigui, M.
    [J]. POLYHEDRON, 2007, 26 (08) : 1603 - 1611
  • [6] Hydrothermal synthesis and characterization of a new zinc phosphate [Zn2.5(HPO4)2(PO4)][C6H10N2] • 5H2O
    Kefi, R.
    Ben Nasr, C.
    Lefebvre, F.
    Rzaigui, M.
    [J]. POLYHEDRON, 2006, 25 (15) : 2953 - 2958
  • [7] Synthesis and characterization of [C4N2H12]1.5[Zn2(PO4) (HPO4)2]•H2O
    Xing, Y
    Ding, H
    Li, GH
    Shi, Z
    Liu, YL
    Pang, WQ
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2003, 19 (08) : 853 - 856
  • [8] Synthesis and characterisation of a new vanadyl oxalatophosphate compound:: (C10H10N2)[(VO)(HPO4)]2(C2O4)
    Shi, FN
    Paz, FAA
    Rocha, J
    Klinowski, J
    Trindade, T
    [J]. INORGANICA CHIMICA ACTA, 2005, 358 (04) : 927 - 932
  • [9] SURFACE IONIZATION OF C4H10N RADICAL
    ZANDBERG, EY
    RASULEV, UK
    [J]. DOKLADY AKADEMII NAUK SSSR, 1968, 178 (02): : 327 - &
  • [10] Synthesis and structure determination of a piperidinium Zn(HPO4)ClC5H12N
    Rayes, A
    Ben Nasr, C
    Rzaigui, M
    [J]. MATERIALS RESEARCH BULLETIN, 2001, 36 (12) : 2229 - 2239
12345