Synthesis and structural characterization of a new layered chlorozincophosphate, Zn(HPO4)Cl•[H3N(CH2)6NH3]0.5

被引：13
|
作者：
Rayes, A [1 ]
Ben Nasr, C [1 ]
Rzaigui, A [1 ]
机构：
[1] Fac Sci, Lab Chim Mat, Zarzouna 7021, Bizerte, Tunisia
来源：
MATERIALS RESEARCH BULLETIN | 2004年 / 39卷 / 4-5期
关键词：
microporous material; chemical synthesis; X-ray diffraction; crystal structure;
D O I：
10.1016/j.materresbull.2003.12.016
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new layered zinc-phosphate Zn(HPO4)Cl.[H3N(CH2)(6)NH3](0.5) was synthesized in acidic conditions at room temperature. It crystallizes in monoclinic space group C2/c (No. 15) with the lattice parameters a = 21.826(3) Angstrom, b = 9.452(7) Angstrom, c = 8.780(1) Angstrom, beta = 109.36(8)degrees, V = 1708.83(1) Angstrom(3), Z = 8, R = 0.036, R-w = 0.047. The structure of this compound is determined by X-ray diffraction and characterized with IR, TGA-DTA/DSC and NMR. The structure consists of inorganic layers, built by PO4 and ZnO3Cl tetrahedra interconnected by common oxygen atoms. The organic entities, located between these layers, perform the 3D cohesion through N-(HO)-O-... or N-(HCl)-Cl-... hydrogen bonds. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：571 / 580
页数：10
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