Synthesis and structure determination of a piperidinium Zn(HPO4)ClC5H12N

被引：10
|
作者：
Rayes, A [1 ]
Ben Nasr, C [1 ]
Rzaigui, M [1 ]
机构：
[1] Fac Sci Zarzouna, Lab Chim Mat, Zarzouna 7021, Bizerte, Tunisia
来源：
MATERIALS RESEARCH BULLETIN | 2001年 / 36卷 / 12期
关键词：
layered compound; crystal growth; X-ray diffraction; crystal structure;
D O I：
10.1016/S0025-5408(01)00702-4
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This article deals with the synthesis and X-ray structure determination of a new bidimentional zincophosphate (ZnPO) with formula Zn(HPO4)ClC5H12N. This phase crystallizes in the orthorhombic space group Pbca (No. 61) with parameters: a = 8.767(2) Angstrom; b = 24.678(7) Angstrom; c = 9.322(2) Angstrom; V = 2016.8(1) Angstrom (3); Z = 8. Structure of this compound is determined: R = 0.026 R-W = 0.033 and characterized with IR, TGA/DSC, and NMR. The structure consists of anionic parallel [Zn(HPO4)Cl](-) sheets alternating with thick slabs of organic molecules (C5H12N)(+). The organic molecules are linked to the anionic sheets through hydrogen bonds. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2229 / 2239
页数：11
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