Synthesis and structure of [Zn6(H2O)8(HPO4)4(HPO3O4)•2 [H2N2C6H16]

被引：0
|
作者：
Reinert, P
Khatyr, A
Marler, B
Patarin, J
机构：
[1] Univ Haute Alsace, Ecole Natl Super Chim Mulhouse, Lab Mat Mineraux, URA CNRS 428, F-68093 Mulhouse, France
[2] Ruhr Univ Bochum, Inst Mineral, D-44780 Bochum, Germany
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1997年 / 34卷 / 11期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new two-dimensional zincophosphate [Zn-6(H2O)(8)(HPO4)(4) (HPO3O)(4)]. 2 H2N2C6N16 was obtained around 0 degrees C from a ZnO/P2O5/R/H2O mixture, R being the N,N,N',N' tetramethylethylenediamine. The crystal structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic a=0.8932(1) nm, b=0.9693(1) nm, c=1.3503(2) nm, beta=96,01(1)degrees, space group P2(1)/c. The structure consists of parallel [Zn-6(H2O)(8)(HPO4)(4)(HPO3O)(4)](4-) sheets in between are located the diprotonated organic molecules. The characterization by P-31 and C-13 solid state nmr spectroscopy is also reported.
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页码：1211 / 1225
页数：15
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