Bis(acetylacetonato-κ2O,O′)(2-amino-1-methyl-1H-benzimidazole-κN3)oxidovanadium(IV)

被引：7
|
作者：
Kadirova, Zukhra Ch. [1 ]
Rahmonova, Dilnoza S. [1 ]
Talipov, Samat A. [2 ]
Ashurov, Jamshid M. [2 ]
Parpiev, Nusrat A. [1 ]
机构：
[1] Natl Univ Uzbekistan, Tashkent 100123, Uzbekistan
[2] Inst Biorgan Chem, Tashkent 100125, Uzbekistan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
CRYSTAL-STRUCTURE; COORDINATION CHEMISTRY; REACTIVITY; COMPLEXES; VANADIUM;
D O I：
10.1107/S1600536809023113
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title mixed-ligand oxidovanadium(IV) compound, [VO(C5H7O2)(2)(C8H9N3)], contains a V-IV atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intramolecular hydrogen bonds between the exo-NH2 group H atoms and acetylacetonate O atoms stabilize the crystal structure.
引用
收藏
页码：M819 / U1236
页数：11
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