Bis(acetylacetonato-κ2O,O′)(2-amino-1-methyl-1H-benzimidazole-κN3)oxidovanadium(IV)

被引：7

作者：

Kadirova, Zukhra Ch. ^{[1
]}

Rahmonova, Dilnoza S. ^{[1
]}

Talipov, Samat A. ^{[2
]}

Ashurov, Jamshid M. ^{[2
]}

Parpiev, Nusrat A. ^{[1
]}

机构：

[1] Natl Univ Uzbekistan, Tashkent 100123, Uzbekistan

[2] Inst Biorgan Chem, Tashkent 100125, Uzbekistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

CRYSTAL-STRUCTURE; COORDINATION CHEMISTRY; REACTIVITY; COMPLEXES; VANADIUM;

D O I：

10.1107/S1600536809023113

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title mixed-ligand oxidovanadium(IV) compound, [VO(C5H7O2)(2)(C8H9N3)], contains a V-IV atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intramolecular hydrogen bonds between the exo-NH2 group H atoms and acetylacetonate O atoms stabilize the crystal structure.

引用

页码：M819 / U1236

页数：11

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