Palladium-catalyzed intermolecular Heck reaction of alkyl halides

被引：103

作者：

Zou, Yinjun ^{[1
]}

Zhou, Jianrong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 28期

基金：

新加坡国家研究基金会;

关键词：

ORGANIC HALIDES; RADICAL ALKENYLATION; COUPLING REACTIONS; SIMPLE ALKENES; BROMIDES; BENZYL; ARYL; OLEFINATION; CYCLIZATION; SECONDARY;

D O I：

10.1039/c4cc00297k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intermolecular Heck reaction of common alkyl halides, a long-standing problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary and secondary alkyl halides are suitable for coupling with aromatic olefins. Single electron transfer from (dppf) Pd-degrees to alkyl halide initiated the catalytic cycle and gave alkyl radicals.

引用

页码：3725 / 3728

页数：4

共 50 条

[21] Palladium-catalyzed intermolecular transthioetherification of aryl halides with thioethers and thioesters
Li, Yahui
Bao, Gao
Wu, Xiao-Feng
CHEMICAL SCIENCE, 2020, 11 (08) : 2187 - 2192
[22] Tetraphosphine/palladium-catalyzed Heck reactions of aryl halides with disubstituted alkenes
Kondolff, I
Doucet, H
Santelli, M
TETRAHEDRON LETTERS, 2003, 44 (46) : 8487 - 8491
[23] Palladium-catalyzed asymmetric intermolecular Mizoroki-Heck reaction for construction of a chiral quaternary carbon center
Zhang, Qing-Song
Wan, Shi-Li
Chen, Di
Ding, Chang-Hua
Hou, Xue-Long
CHEMICAL COMMUNICATIONS, 2015, 51 (61) : 12235 - 12238
[24] Visible-Light-Induced Palladium-Catalyzed Intermolecular Narasaka-Heck Reaction at Room Temperature
Feng, Liyan
Guo, Lin
Yang, Chao
Zhou, Jia
Xia, Wujiong
ORGANIC LETTERS, 2020, 22 (10) : 3964 - 3968
[25] Palladium-Catalyzed Radical-Type Transformations of Alkyl Halides
Zhou, Wen-Jun
Zhang, Yihan
Cao, Guangmei
Liu, Huidong
Yu, Da-Gang
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (06) : 1322 - 1337
[26] Palladium-Catalyzed Carbonylative Heck-Type Reactions of Alkyl Iodides
Bloome, Kayla S.
Alexanian, Erik J.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (37) : 12823 - 12825
[27] Palladium-catalyzed coupling reaction of alkenylgalliums with aryl halides
Mikami, S
Yorimitsu, H
Oshima, K
SYNLETT, 2002, (07) : 1137 - 1139
[28] Synthesis of isoquinolines by palladium-catalyzed cyclization, followed by a Heck reaction
Huang, QH
Larock, RC
TETRAHEDRON LETTERS, 2002, 43 (19) : 3557 - 3560
[29] Palladium-catalyzed reaction of allyl halides with α-diazocarbonyl compounds
Chen, Shufeng
Wang, Jianbo
CHEMICAL COMMUNICATIONS, 2008, (35) : 4198 - 4200
[30] Palladium-catalyzed synthesis of indoles via intramolecular Heck reaction
Yang, Hailong
Sun, Peng
Zhu, Yan
Yan, Hong
Lu, Linhua
Liu, Defu
Rong, Guangwei
Mao, Jincheng
CATALYSIS COMMUNICATIONS, 2013, 38 : 21 - 25

← 1 2 3 4 5 →