Hierarchically aligned porous scaffold by ice-segregation-induced self-assembly and thermally triggered electrostatic self-assembly of oppositely charged thermosensitive microgels

被引:20
|
作者
Yao, Xiang [2 ]
Yao, Hongwei [1 ]
Li, Yuanting [2 ]
机构
[1] Qingdao Univ, Dept Polymer Sci & Engn, Qingdao 266071, Peoples R China
[2] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China
关键词
NANOPARTICLES;
D O I
10.1039/b909059b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a new method for the fabrication of a 3-dimensional hierarchical aligned porous scaffold by a combined ice-segregation-induced self-assembly and thermally triggered electrostatic self-assembly method. The oppositely charged thermosensitive microgels were used as the building blocks of the scaffold. The porous structure can be controlled by adjusting both the directional freezing conditions and microgel components. The scaffold thus prepared may survive in a physiological environment (37 degrees C in water) and has great potential in biomedical applications such as tissue engineering.
引用
下载
收藏
页码:6516 / 6520
页数:5
相关论文
共 50 条
  • [31] Sugarcane bagasse as the scaffold for mass production of hierarchically porous carbon monoliths by surface self-assembly
    Huang, Chun-Hisen
    Doong, Ruey-An
    MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 147 (01) : 47 - 52
  • [32] Self-Assembly of Faceted Particles Triggered by a Moving Ice Front
    Bouville, Florian
    Maire, Eric
    Deville, Sylvain
    LANGMUIR, 2014, 30 (29) : 8656 - 8663
  • [33] Ice-templated materials:: Sophisticated structures exhibiting enhanced functionalities obtained after unidirectional freezing and ice-segregation-induced self-assembly
    Gutierrez, Maria C.
    Ferrer, Maria L.
    del Monte, Francisco
    CHEMISTRY OF MATERIALS, 2008, 20 (03) : 634 - 648
  • [34] Kinetics and Structure during Self-Assembly of Oppositely Charged Proteins in Aqueous Solution
    Salvatore, Delphine
    Croguennec, Thomas
    Bouhallab, Said
    Forge, Vincent
    Nicolai, Taco
    BIOMACROMOLECULES, 2011, 12 (05) : 1920 - 1926
  • [35] Effects of oppositely charged moieties on the self-assembly and biophysicochemical properties of polyurethane micelles
    Pan, Zhicheng
    Yang, Guangxuan
    Liu, Jian
    Yuan, Jinfeng
    Pan, Mingwang
    Li, Jiehua
    Tan, Hong
    JOURNAL OF MATERIALS CHEMISTRY B, 2022, 10 (23) : 4431 - 4441
  • [36] Two-dimensional clusters from the self-assembly of oppositely charged particles
    Rodrigues, S. G.
    Pais, A. A. C. C.
    Marques, J. M. C.
    CHEMICAL PHYSICS LETTERS, 2018, 706 : 586 - 593
  • [37] Oppositely Charged, Stimuli-Responsive Anisotropic Nanoparticles for Colloidal Self-Assembly
    Hwang, Eun Young
    Lee, Jae Sang
    Lim, Dong Woo
    LANGMUIR, 2019, 35 (13) : 4589 - 4602
  • [38] The electrostatic self-assembly of microgels on polymer brushes and its effects on interfacial friction
    Zhang, Ran
    Ma, Shuanhong
    Liu, Guoqiang
    Cai, Meirong
    Ye, Qian
    Yu, Bo
    Zhou, Feng
    JOURNAL OF APPLIED POLYMER SCIENCE, 2016, 133 (46)
  • [39] Self-assembly of polystyrene nanoparticles induced by ice templating
    Yan, Jia
    Wu, Zhanjun
    Tan, Li
    SECOND INTERNATIONAL CONFERENCE ON SMART MATERIALS AND NANOTECHNOLOGY IN ENGINEERING, 2009, 7493
  • [40] Electrostatic self-assembly of oppositely charged copolymers and surfactants:: A light, neutron, and X-ray scattering study
    Berret, JF
    Vigolo, B
    Eng, R
    Hervé, P
    Grillo, I
    Yang, L
    MACROMOLECULES, 2004, 37 (13) : 4922 - 4930