Production of high purity hydrogen by ethanol steam reforming in membrane reactor

被引：47
|
作者：
Mironova, E. Yu. [1 ]
Ermilova, M. M. [1 ]
Orekhova, N. V. [1 ]
Muraviev, D. N. [2 ]
Yaroslavtsev, A. B. [1 ,3 ]
机构：
[1] Russian Acad Sci, AV Topchiev Inst Petrochem Synth, Moscow 119991, Russia
[2] UAB, Dept Chem, Anal Chem Unit, Bellaterra 08193, Barcelona, Spain
[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
CATALYSIS TODAY | 2014年 / 236卷
关键词：
Ethanol steam reforming; Pd-Ru membrane reactor; Nanodiamond-supported metal catalysts; POLYMER ELECTROLYTE MEMBRANES; BIO-ETHANOL; NANOCATALYSTS; TEMPERATURE; CONVERSION; BIOMASS;
D O I：
10.1016/j.cattod.2014.01.014
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 911. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：64 / 69
页数：6
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