Synthesis, Crystal Structure and Catalytic Activity of a 1D Chained Ca(II) Coordination Polymer with 3,5-Bis(4-pyridylmethoxy)benzoate Ligand

被引：9
|
作者：
Wang, Li-Hua [1 ]
Wang, Xin [2 ]
Tai, Xi-Shi [3 ]
机构：
[1] Weifang Univ, Coll Informat & Engn, Weifang 261061, Peoples R China
[2] Qinghai Normal Univ, Dept Chem, Xining 810008, Peoples R China
[3] Weifang Univ, Coll Chem & Chem Engn, Weifang 261061, Peoples R China
来源：
CRYSTALS | 2017年 / 7卷 / 03期
关键词：
3,5-bis(4-pyridylmethoxy)benzoate; 1D chained structure; Ca(II) coordination polymer; synthesis; structural characterization; ANTITUMOR-ACTIVITY; LUMINESCENT PROPERTY; ACID; COMPLEX; FRAMEWORKS; SERIES;
D O I：
10.3390/cryst7030072
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new 1D chained Ca(II) coordination polymernamely, [CaL2(H2O)(2)](n) (HL = 3,5-bis(4-pyridylmethoxy)benzoic acid)was synthesized though the reaction of Ca(ClO4)(2)4H(2)O, 3,5-bis(4-pyridylmethoxy)benzoic acid and NaOH in H2O/CH3CH2OH (v:v = 1:2) solution. Its structure was determined by elemental analysis, infrared spectrum, and single-crystal XRD. Structural analyses show that each Ca(II) ion is eight-coordinated by six oxygen atoms of four 3,5-bis(4-pyridylmethoxy)benzoate ligands and two oxygen atoms of two coordinated H2O molecules to form a square-antiprismatic CaO8 polyhedron. The Ca(II) complex displays a 1D chained structure constructed by the bridging effect of the bidentate carboxyl group of 3,5-bis(4-pyridylmethoxy)benzoate ligand. The catalytic activity of the Ca-complex was tested for the preparation of propargylamine in the A(3) coupling reaction.
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页数：7
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