Synthesis, Crystal Structure and Catalytic Activity of a 1D Chained Ca(II) Coordination Polymer with 3,5-Bis(4-pyridylmethoxy)benzoate Ligand

被引：9
|
作者：
Wang, Li-Hua [1 ]
Wang, Xin [2 ]
Tai, Xi-Shi [3 ]
机构：
[1] Weifang Univ, Coll Informat & Engn, Weifang 261061, Peoples R China
[2] Qinghai Normal Univ, Dept Chem, Xining 810008, Peoples R China
[3] Weifang Univ, Coll Chem & Chem Engn, Weifang 261061, Peoples R China
来源：
CRYSTALS | 2017年 / 7卷 / 03期
关键词：
3,5-bis(4-pyridylmethoxy)benzoate; 1D chained structure; Ca(II) coordination polymer; synthesis; structural characterization; ANTITUMOR-ACTIVITY; LUMINESCENT PROPERTY; ACID; COMPLEX; FRAMEWORKS; SERIES;
D O I：
10.3390/cryst7030072
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new 1D chained Ca(II) coordination polymernamely, [CaL2(H2O)(2)](n) (HL = 3,5-bis(4-pyridylmethoxy)benzoic acid)was synthesized though the reaction of Ca(ClO4)(2)4H(2)O, 3,5-bis(4-pyridylmethoxy)benzoic acid and NaOH in H2O/CH3CH2OH (v:v = 1:2) solution. Its structure was determined by elemental analysis, infrared spectrum, and single-crystal XRD. Structural analyses show that each Ca(II) ion is eight-coordinated by six oxygen atoms of four 3,5-bis(4-pyridylmethoxy)benzoate ligands and two oxygen atoms of two coordinated H2O molecules to form a square-antiprismatic CaO8 polyhedron. The Ca(II) complex displays a 1D chained structure constructed by the bridging effect of the bidentate carboxyl group of 3,5-bis(4-pyridylmethoxy)benzoate ligand. The catalytic activity of the Ca-complex was tested for the preparation of propargylamine in the A(3) coupling reaction.
引用
收藏
页数：7
相关论文
共 50 条
  • [1] A double-layered zinc(II) coordination polymer with the ligand 3,5-bis(carboxylatomethoxy)benzoate
    Cen, Zhong-Min
    Li, Fa-Si
    Ni, Qing-Ling
    Wang, Xiu-Jian
    Li, Bin
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 : M17 - M20
  • [2] Synthesis, Crystal Structure and Antibacterial Activity of 1D Chain Ca(II) Coordination Polymer
    Tai, Xi-Shi
    [J]. ADVANCED RESEARCH ON MATERIAL ENGINEERING, CHEMISTRY AND BIOINFORMATICS, PTS 1 AND 2 (MECB 2011), 2011, 282-283 : 96 - 99
  • [3] Synthesis, crystal structure and properties of a 1D cadmium(II) coordination polymer with 2,6-dirnethyl-3,5-bis(pyrazo-3-yl)pyridine
    Fan, Wen Tao
    Zhu, Han
    Xu, Quan Qing
    Kou, Jun Feng
    Liu, Feng Yi
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2019, 58 (03): : 326 - 329
  • [4] A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property
    Tai, Xi-Shi
    You, Hai-Ying
    [J]. CRYSTALS, 2015, 5 (04): : 608 - 616
  • [5] Synthesis, Crystal Structure, and Catalytic Properties of a New Cobalt (II) 1D Coordination Polymer
    Hou, Wen Long
    Dong, Gui-Ying
    Zhao, Yan Qin
    Zhang, Wei-Guo
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (09) : 1186 - 1189
  • [6] Synthesis, crystal structure and magnetism of 1D manganese(II) coordination polymer with thiocyanato as bridging ligand
    Shi, J-M.
    Chen, J-N.
    Liu, L-D.
    [J]. POLISH JOURNAL OF CHEMISTRY, 2006, 80 (11) : 1909 - 1913
  • [7] Synthesis, crystal structure and magnetism of 1D cobalt(II) coordination polymer with thiocyanate as bridging ligand
    Shi, J.-M.
    Chen, J.-N.
    Wu, C.-J.
    Ma, J.-P.
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (18) : 2009 - 2013
  • [8] Synthesis, Crystal Structure and Properties of 1D Manganese(II) Coordination Polymer
    Fang Xiang-Qian
    Chen Peng-Gang
    Zhu Zhi-Biao
    Deng Zhao-Peng
    Gao Shan
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (09) : 1733 - 1737
  • [9] Crystal structure, thermal and fluorescent properties of a 1D Cd(II) coordination polymer based on the bis(benzimidazole) ligand
    X. Du
    Y. Y. Wang
    Y. Q. Zhao
    G. H. Cui
    [J]. Journal of Structural Chemistry, 2014, 55 : 734 - 738
  • [10] Crystal structure, thermal and fluorescent properties of a 1D Cd(II) coordination polymer based on the bis(benzimidazole) ligand
    Du, X.
    Wang, Y. Y.
    Zhao, Y. Q.
    Cui, G. H.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (04) : 734 - 738
12345