Synthesis, crystal structure and magnetism of 1D cobalt(II) coordination polymer with thiocyanate as bridging ligand

被引：40
|
作者：
Shi, J.-M. [1 ]
Chen, J.-N. [1 ]
Wu, C.-J. [1 ]
Ma, J.-P. [1 ]
机构：
[1] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 18期
基金：
中国国家自然科学基金;
关键词：
crystal structure; cobalt(II) complex; magnetism;
D O I：
10.1080/00958970701223345
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A one- dimensional coordination polymer [ Co(mu(1,3)-NCS)(2)(npdo)(2)](n) (npdo=4- nitropyridine N- oxide) has been synthesized and structurally determined by X- ray crystallography. The complex crystallizes in the orthorhombic space group of Pbcn with a=22.688( 5) angstrom, b=7.2636(17) angstrom, c=10.299(2) angstrom. Adjacent Co(II) ions are coordinated by two mu(1,3)-SCN(-) bridging ligands, forming a one- dimensional chain along the c axis and the npdo coordinates to Co( II) ion as a terminal ligand. The thermal variation of the magnetic moments of the complex reflects the antiferromagnetic interaction between the bridged Co( II) ions above 20K and the ferromagnetic transition or the strong short- range spin interaction below 20 K.
引用
收藏
页码：2009 / 2013
页数：5
相关论文
共 50 条
  • [1] Synthesis, crystal structure and magnetism of 1D manganese(II) coordination polymer with thiocyanato as bridging ligand
    Shi, J-M.
    Chen, J-N.
    Liu, L-D.
    POLISH JOURNAL OF CHEMISTRY, 2006, 80 (11) : 1909 - 1913
  • [2] Synthesis, Crystal Structure, and Catalytic Properties of a New Cobalt (II) 1D Coordination Polymer
    Hou, Wen Long
    Dong, Gui-Ying
    Zhao, Yan Qin
    Zhang, Wei-Guo
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (09) : 1186 - 1189
  • [3] Synthesis, Crystal Structure and Properties of 1D Manganese(II) Coordination Polymer
    Fang Xiang-Qian
    Chen Peng-Gang
    Zhu Zhi-Biao
    Deng Zhao-Peng
    Gao Shan
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (09) : 1733 - 1737
  • [4] Synthesis, structure and magnetic properties of a cobalt(II) mesoxalate 1D coordination polymer
    Gil-Hernandez, Beatriz
    Sanchiz, Joaquin
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2021, 647 (05): : 485 - 489
  • [5] A 1D coordination polymer of copper(II) with three different bridging anions: synthesis, crystal structure and magnetic behaviour
    Mukherjee, PS
    Maji, TK
    Mostafa, G
    Hibbs, W
    Chaudhuri, NR
    NEW JOURNAL OF CHEMISTRY, 2001, 25 (05) : 760 - 763
  • [6] Synthesis, Crystal Structure and Thermal Stability of 1D Copper(II) Coordination Polymer
    Xu Jing
    Deng Zhao-Peng
    Huo Li-Hua
    Gao Shan
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (09) : 1748 - 1752
  • [7] Synthesis, Crystal Structure and Photoluminescence of a New 1D Cd(II) Coordination Polymer
    Liu Guo-Cheng
    Zhang Jin-Xia
    Wang Xiu-Li
    Chen Yong-Qiang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (05) : 913 - 916
  • [8] Synthesis and Crystal Structure of Iron(II) Coordination Polymer Composed of 1D Chains
    Che Guang-Bo
    Li Xiu-Ying
    Xu Zhan-Lin
    Liu Chun-Bo
    Wang Qing-Wei
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (03) : 556 - 559
  • [9] A NOVEL HELICAL CHAINLIKE COBALT( II) COORDINATION POLYMER CONTAINING 1D TRIGONAL CHANNELS: SYNTHESIS, CRYSTAL STRUCTURE AND PROPERTIES
    Cai, Jin-Hua
    Zhong, Fan
    Chen, Wen-Tong
    Jiang, Yi-Min
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2011, 76 (12) : 1955 - 1965
  • [10] Synthesis, Crystal Structure and Antibacterial Activity of 1D Chain Ca(II) Coordination Polymer
    Tai, Xi-Shi
    ADVANCED RESEARCH ON MATERIAL ENGINEERING, CHEMISTRY AND BIOINFORMATICS, PTS 1 AND 2 (MECB 2011), 2011, 282-283 : 96 - 99
12345