Synthesis, characterization and biological activity evaluation of Pt(II), Pd(II), Co(III) and Ni(II) complexes with N-heteroaromatic selenosemicarbazones

被引：37

作者：

Todorovic, Tamara R. ^{[1
]}

Bacchi, Alessia ^{[2
]}

Sladic, Dusan M. ^{[1
]}

Todorovic, Nina M. ^{[3
]}

Bozic, Tatjana T. ^{[1
]}

Radanovic, Dusanka D. ^{[3
]}

Filipovic, Nenad R. ^{[4
]}

Pelizzi, Giancarlo ^{[2
]}

Andelkovic, Katarina K. ^{[1
]}

机构：

[1] Univ Belgrade, Fac Chem, Belgrade 11000, Serbia

[2] Univ Parma, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy

[3] Univ Belgrade, Inst Chem Technol & Met, Belgrade 11000, Serbia

[4] Univ Belgrade, Fac Agr, Belgrade 11081, Serbia

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 10期

关键词：

Selenosemicarbazones; d-Metal complexes; Structural study; Biological activity; CRYSTAL-STRUCTURE; THIOSEMICARBAZONES; CD(II); ZN(II); 2-ACETYLPYRIDINE; SEMICARBAZONES;

D O I：

10.1016/j.ica.2009.04.047

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five new complexes of Pt(II), Pd(II), Co(III) and Ni(II) with 2-pyridine(quinoline) carboxaldehyde selenose-micarbazones were synthesized and characterized. Crystal structures of Pt(II) complex with the pyridine derivative and Co(III) complex with the quinoline derivative were determined. In all complexes the ligands were coordinated through N2Se donor atom set forming either square-planar (Pt, Pd) or octahedral (Co, Ni) geometry. All complexes showed biological activity. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：3813 / 3820

页数：8

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