Novel Three-Dimensional Coordination Polymers Based on [Mo6Se8(CN)6]7- Anions and Mn2+ Cations

被引：19
|
作者：
Brylev, Konstantin A. [1 ]
Naumov, Nikolay G. [1 ]
Virovets, Alexander V. [1 ]
Kim, Sung-Jin [2 ]
Fedorov, Vladimir E. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Ewha Womans Univ, Seoul 120750, South Korea
来源：
JOURNAL OF CLUSTER SCIENCE | 2009年 / 20卷 / 01期
关键词：
Molybdenum; Cluster Compounds; Cyanides; Crystal structure; MOLECULAR BUILDING-BLOCKS; PRUSSIAN BLUE ANALOGS; BRIDGED RE(6)Q(8) Q; CRYSTAL-STRUCTURE; FRAMEWORK MATERIALS; CLUSTER COMPLEXES; SE; CHALCOCYANIDE; DIMENSIONALITY; TRANSFORMATION;
D O I：
10.1007/s10876-008-0215-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three novel coordination polymers K-5[MnMo6Se8(CN)(6)] center dot A 8H(2)O (1), (Me4N)(4)[{Mn(H2O)(2)}(1.5)Mo6Se8(CN)(6)] center dot A 4H(2)O (2), and K-3[{Mn-2(H2O)(4)}Mo6Se8(CN)(6)] center dot A 7H(2)O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen-N,N'-bis(salicylidene)ethylenediamine) on an aqueous solution of K-7[Mo6Se8(CN)(6)] center dot A 8H(2)O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN)(6)](7-) cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.
引用
收藏
页码：165 / 176
页数：12
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