A turn-on Schiff-base fluorescence sensor for Mg2+ ion and its practical application

被引:27
|
作者
Kao, Min-Hsiu [1 ]
Chen, Ting-Yu [1 ]
Cai, You-Ru [1 ]
Hu, Ching-Han [1 ]
Liu, Yen-Wen [1 ]
Jhong, Yi [1 ]
Wu, An-Tai [1 ]
机构
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
关键词
Quinoline; Sensor; Schiff-base; Reversibility; CHELATION-ENHANCED FLUORESCENCE; MAGNESIUM; DESIGN; PROBES;
D O I
10.1016/j.jlumin.2015.08.036
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A simple quinoline derivative (quinoline-base sensor) was synthesized and investigated by its sensing properties towards various metal ions in CH3CN. Quinoline-base sensor showed a highly selective fluorescent enhancement towards Mg2+ The association constant of a 1:1 complex between quinoline-base sensor and Mg2+ was determined as 1.91 x 10(7) M-1. The detection limit of quinoline-base sensor for the analysis of Mg2+ ion was determined as 19.1 ppb; this value is below the maximum permissible level for drinking water. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:156 / 160
页数:5
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