A turn-on and reversible Schiff base fluorescence sensor for Al3+ ion

被引:108
|
作者
Chen, Chang-Hung [1 ]
Liao, De-Jhong [1 ]
Wan, Chin-Feng [2 ]
Wu, An-Tai [1 ]
机构
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
[2] Chung Shan Med Univ, Sch Appl Chem, Taichung 40201, Taiwan
关键词
PHOTOINDUCED ELECTRON-TRANSFER; ALUMINUM IONS; ENHANCED SENSOR; HYBRID LIGAND; CHEMOSENSOR; PROBE; SCAFFOLD;
D O I
10.1039/c3an00004d
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A simple Schiff-base receptor 2 was prepared. It exhibits an "off-on-type" mode with high sensitivity in the presence of Al3+. The receptor 2 exhibited a high association constant with submicromolar detection for Al3+ in EtOH-H2O (95 : 5 v/v) solution. The addition of EDTA quenches the fluorescence of the receptor 2 center dot Al3+ complex offering receptor 2 as a reversible chemosensor.
引用
收藏
页码:2527 / 2530
页数:4
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