A turn-on Schiff base fluorescence sensor for zinc ion

被引:134
|
作者
Hsieh, Wei Hsun [1 ]
Wan, Chin-Feng [2 ]
Liao, De-Jhong [1 ]
Wu, An-Tai [1 ]
机构
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
[2] Chung Shan Med Univ, Sch Appl Chem, Taichung 40201, Taiwan
关键词
Chemosensor; Schiff base; Fluorescence; Turn-on; BIOLOGICAL-SYSTEMS; ZN2+; CHEMOSENSOR; MOLECULE; RECEPTOR; ZN(II); MOIETY; PROBE;
D O I
10.1016/j.tetlet.2012.08.058
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple Schiff base type fluorescent receptor 1 was prepared and evaluated for its fluorescence response to heavy metal ions. Receptor 1 exhibits an 'off-on-type' mode with high selectivity in the presence of Zn2+ ion. The selectivity of 1 for Zn2+ is the consequence of combined effects of chelation-enhanced fluorescence (CHEF), C=N isomerization, and inhibition of photoinduced electron transfer (PET). Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:5848 / 5851
页数:4
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