Hydroformylation of olefins catalysed with bimetallic systems: HRh{P(OPh)(3)}(4)+cp(2)ZrH(CH(2)PPh(2)) and HRh(CO){P(OPh)(3)}(3)+cp(2)ZrH(CH(2)PPh(2))

被引：10

作者：

Trzeciak, AM

Ziotkowski, JJ

Choukroun, R

机构：

[1] UNIV WROCLAW,FAC CHEM,PL-50383 WROCLAW,POLAND

[2] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 525卷 / 1-2期

关键词：

hydroformylation; bimetallic system; rhodium; zirconium; olefins;

D O I：

10.1016/S0022-328X(96)06499-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic activity of bimetallic systems containing the rhodium complex HRh{P(OPh)(3)}(4) or HRh(CO){P(OPh)(3)}(3) and the Zr(IV) complex cp(2)ZrH(CH(2)PPh(2)) was tested in the hydroformylation reaction of 1-hexene and E-,Z-2-hexene. An increase in n/iso ratio (from 2.2 to 3.5 in the case of HRh{P(OPh)(3)}(4) and from 0.4 to 3.7 in the case of HRh(CO){P(OPh)(3)}(3)) was observed in 1-hexene hydroformylation in the presence of cp(2)ZrH(CH(2)PPh(2)).

引用

页码：145 / 149

页数：5

共 50 条

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