Synthesis, characterization, and cis-trans isomerization studies of cis-[PdCl2{Ph2P(CH2CH2O) 3CH2CH2PPh2-P,P′}] and trans-[PtCl2{Ph2P(CH2CH2O) 3CH2CH2PPh2-P,P′}] metallacrown ethers

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Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, Birmingham, AL 35294-1240, United States ^{[1
]}

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Eur. J. Inorg. Chem. | / 30卷 / 4710-4718期

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Cis and trans isomers - Cis/trans Isomerization - Crown-ethers - Ether bond - First order kinetics - H NMR spectroscopy - Isomerisation - Isomerization reaction - Oligomerizations - Transition state;

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[1] Synthesis, Characterization, and cis-trans Isomerization Studies of cis-[PdCl2{Ph2P(CH2CH2O)3CH2CH2PPh2-P,P′}] and trans-[PtCl2{Ph2P(CH2CH2O)3CH2CH2PPh2-P,P′}] Metallacrown Ethers
Owens, Samuel B., Jr.
Smith, Dale C., Jr.
Lake, Charles H.
Gray, Gary M.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (30) : 4710 - 4718
[2] Reversible polymerization and cis-trans isomerization equilibria in [PdCl2{Ph2P(CH2CH2O)4CH2CH2PPh2-P,P′}] metallacrown ethers
Smith, DC
Gray, GM
INORGANIC CHEMISTRY, 1998, 37 (08) : 1791 - 1797
[3] Reversible Polymerization and Cis-Trans Isomerization Equilibria in [PdCl2{Ph2P(CH2-CH2O)4CH2CH2 PPh2 -P,P'}] Metallacrown Ethers
Inorganic Chemistry, 37 (08):
[4] CIS-MO(CO)4(PH2P(CH2CH2O)NCH2CH2PPH2) (N = 3-5) METALLACROWN ETHERS - X-RAY CRYSTAL-STRUCTURE OF CIS-MO(CO)4(PH2P(CH2CH2O)3CH2CH2PPH2)
VARSHNEY, A
GRAY, GM
INORGANIC CHEMISTRY, 1991, 30 (08) : 1748 - 1754
[5] An NMR spectroscopic study of the binding of alkali metal cations and methanol by cis-Mo(CO)4{Ph2P(CH2CH2O)n CH2CH2PPh2-P,P') (n = 4, 5) metallacrown ethers. The X-ray crystal structures of cis-Mo(CO)4{Ph2P(CH2CH2O)4 CH2CH2PPh2-P,P'} QQ MeOH and cis-Mo(CO)4{Ph2P (CH2CH2)4CH2CH2PPh2-P,P'} QQ H2O
Inorg Chim Acta, 1-2 (229):
[6] [CIS,CIS,TRANS-RUCL2(CO)(2)(PH(2)P(CH2CH2O)(N)CH(2)CH(2)PPH(2)-P,P')](M) (N=4, 5, M=1,2,...) METALLACROWN X-RAY CRYSTAL-STRUCTURES OF CIS,CIS,TRANS-RUCL2(CO)(2)(PH(2)P(CH2CH2O)(4)CH(2)CH(2)PPH(2)-P,P'), A COMPLEX WHICH EXHIBITS ROTATIONAL ISOMERS IN THE SOLID-STATE AND [CIS,CIS,TRANS-RUCL2(CO)(2)-(MU-PH(2)P(CH2CH2O)(4)CH(2)CH(2)PPH(2)-P,P')](2), AN UNUSUAL DIMETALLACROWN ETHER
GRAY, GM
VARSHNEY, A
DUFFEY, CH
ORGANOMETALLICS, 1995, 14 (01) : 238 - 244
[7] SYNTHESES AND REACTIONS OF THE CIS-PTCL2(PH2P(CH2CH2O)NCH2CH2PPH2-P,P')(N = 3-5) METALLACROWN ETHER COMPLEXES - THE X-RAY CRYSTAL-STRUCTURES OF THE N = 4 AND 5 COMPLEXES AND OF [CIS-PT(PH2P(CH2CH2O)4CH2CH2PPH2-P,P',O)(H2O)](BF4)2
VARSHNEY, A
WEBSTER, ML
GRAY, GM
INORGANIC CHEMISTRY, 1992, 31 (12) : 2580 - 2587
[8] An NMR spectroscopic study of the binding of alkali metal cations and methanol by cis-Mo(CO)(4){Ph2P(CH2CH2O)(n)CH2CH2PPh2-P,P'} (n=4, 5) metallacrown ethers. The X-ray crystal structures of cis-Mo(CO)(4){Ph2P(CH2CH2O)(4)CH2CH2PPh2-P,P'}center dot MeHO and cis-Mo(CO)(4){Ph2P(CH2CH2O)(4)CH2CH2PPh2-P,P'}center dot H2O (vol 246, pg 229, 1996)
Gray, GM
Fish, FP
Duffey, CH
INORGANICA CHIMICA ACTA, 1997, 261 (02) : 233 - 233
[9] An NMR spectroscopic study of the binding of alkali metal cations and methanol by cis-Mo(CO)4{Ph2P(CH2CH2O) nCH2CH2PPh2-P,P′} (n = 4, 5) metallacrown ethers. The X-ray crystal structures of cis-Mo(Co)4{Ph2P(CH2CH2O) 4CH2CH2PPh2-P,P′}·MeOH
Department of Chemistry, University of Alabama at Birmingham, CHEM 2015 UAB Station, Birmingham, AL 35294, United States
不详
Inorg. Chim. Acta, 1-2 SPEC. ISSUE (229-240):
[10] An NMR spectroscopic study of the binding of alkali metal cations and methanol by cis-Mo(CO)(4){Ph(2)P(CH2CH2O)(n)CH(2)CH(2)PPh(2)-P,P'} (n=4,5) metallacrown ethers. The X-ray crystal structures of cis-Mo(CO)(4){Ph(2)P(CH2CH2O)(4)CH(2)CH(2)PPh(2)-P,P'}center dot MeOH and cis-Mo(CO)(4){Ph(2)P(CH2CH2O)(4)CH(2)CH(2)PPh(2)-P,P'}center dot H2O (vol 246, pg 229, 1996)
Gray, GM
Fish, FP
Duffey, CH
INORGANICA CHIMICA ACTA, 1997, 254 (01) : 201 - 201

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