Catalytic upgrading of soybean oil methyl esters by partial hydrogenation using Pd catalysts

被引：38
|
作者：
Thunyaratchatanon, Chachchaya [1 ]
Luengnaruemitchai, Apanee [1 ]
Chollacoop, Nuwong [2 ]
Yoshimura, Yuji [3 ]
机构：
[1] Chulalongkorn Univ, Petr & Petrochem Coll, Soi Chula 12,Phayathai Rd, Bangkok 10330, Thailand
[2] Natl Met & Mat Technol Ctr, Klongluang 12120, Pathumthani, Thailand
[3] Natl Inst Adv Ind Sci & Technol, Tsukuba Cent 5, Tsukuba, Ibaraki 3058565, Japan
来源：
FUEL | 2016年 / 163卷
关键词：
Soybean oil; Biodiesel; Partial hydrogenation; Oxidative stability; Cold flow properties; NOBLE-METAL CATALYSTS; BIODIESEL PRODUCTION; SELECTIVE HYDROGENATION; SULFUR TOLERANCE; LOW-TEMPERATURE; VEGETABLE-OILS; SILICA; PLATINUM; ACID; SUPPORT;
D O I：
10.1016/j.fuel.2015.09.026
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Fatty acid methyl esters derived from soybean oil were partially hydrogenated over three types of catalysts-Pd, Pt, and Ni-supported on SiO2. The effect of the sulfur compounds on catalytic activity of the three noble metals was investigated. In both hydrogenated biodiesel with and without additional sulfur compounds, the turnover frequency (TOF) for partial hydrogenation over Pd/SiO2 was greater than that over the Pt/SiO2 and Ni/SiO2 catalysts. On the other hand, Pt/SiO2 exhibited the most sulfur tolerance. Partially hydrogenated biodiesel were found to have better oxidative stability compared to non-hydrogenated biodiesel. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8 / 16
页数：9
相关论文
共 50 条
  • [21] KINETICS OF CATALYTIC TRANSFER HYDROGENATION OF SOYBEAN OIL
    SMIDOVNIK, A
    PLAZL, I
    KOLOINI, T
    CHEMICAL ENGINEERING JOURNAL AND THE BIOCHEMICAL ENGINEERING JOURNAL, 1993, 51 (03): : B51 - B56
  • [22] KINETICS OF CATALYTIC TRANSFER HYDROGENATION OF SOYBEAN OIL
    SMIDOVNIK, A
    KOBE, J
    LESKOVSEK, S
    KOLOINI, T
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1994, 71 (05) : 507 - 511
  • [23] CATALYTIC TRANSFER HYDROGENATION OF SOYBEAN OIL METHYL ESTER USING INORGANIC FORMIC ACID SALTS AS DONORS.
    Arkad, O.
    Wiener, H.
    Garti, N.
    Sasson, Y.
    JAOCS, Journal of the American Oil Chemists' Society, 1987, 64 (11): : 1529 - 1532
  • [24] Catalytic behavior of ruthenium in soybean oil hydrogenation
    Cizmeci, Melih
    Musavi, Anar
    Tekin, Aziz
    Kayahan, Muammer
    EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2009, 111 (06) : 607 - 611
  • [25] SELECTIVE HYDROGENATION OF SOYBEAN OIL METHYL ESTER
    BAILAR, JC
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1970, 47 (02) : A88 - &
  • [26] CATALYTIC-HYDROGENATION OF ESTERS OVER PD/ZNO
    WEHNER, PS
    GUSTAFSON, BL
    JOURNAL OF CATALYSIS, 1992, 135 (02) : 420 - 426
  • [27] Improved catalytic upgrading of simulated bio-oil via mild hydrogenation over bimetallic catalysts
    Chen, Junhao
    Wang, Shurong
    Lu, Liang
    Zhang, Xing
    Liu, Yixi
    FUEL PROCESSING TECHNOLOGY, 2018, 179 : 135 - 142
  • [28] Intensification of catalytic transfer hydrogenation of fatty acid methyl esters by using ultrasound
    Zhang, Linye
    Liu, Kun
    Wei, Guangtao
    Gao, Lei
    Xin, Zongwu
    Li, Junyu
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2022, 170
  • [29] Studies in catalytic transfer hydrogenation of soybean oil using ammonium formate as donor over 5% Pd/C catalyst
    Tike, Manoj A.
    Mahajani, Vijaykumar V.
    CHEMICAL ENGINEERING JOURNAL, 2006, 123 (1-2) : 31 - 41
  • [30] CATALYTIC TRANSFER HYDROGENATION OF SOYBEAN OIL METHYL-ESTER USING INORGANIC FORMIC-ACID SALTS AS DONORS
    ARKAD, O
    WIENER, H
    GARTI, N
    SASSON, Y
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1987, 64 (11) : 1529 - 1532
12345