Total Spontaneous Resolution of Five-Coordinate Complexes

被引：37
|
作者：
Lennartson, Anders [1 ]
Hakansson, Mikael [1 ]
机构：
[1] Univ Gothenburg, Dept Chem, S-41296 Gothenburg, Sweden
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 32期
基金：
瑞典研究理事会;
关键词：
asymmetric synthesis; chiral resolution; circular dichroism; five-coordinate complexes; structure elucidation; ABSOLUTE ASYMMETRIC-SYNTHESIS; CHIRAL-SYMMETRY-BREAKING; GRIGNARD-REAGENTS;
D O I：
10.1002/anie.200902206
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Talking about a resolution: Bulk quantities of five-coordinate complexes have been resolved for the first time using zinc and cadmium diethyldithiocarbamate species. The stereochemical outcome can be controlled by seeding with the desired isomer, giving access to either enantiomer in high enantiomeric excess and yield. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5869 / 5871
页数：3
相关论文
共 50 条
  • [1] Five-Coordinate Platinum(IV) Complexes
    Grice, Kyle A.
    Scheuermann, Margaret L.
    Goldberg, Karen I.
    HIGHER OXIDATION STATE ORGANOPALLADIUM AND PLATINUM CHEMISTRY, 2011, 35 : 1 - 27
  • [2] Total spontaneous resolution of nine-coordinate complexes
    Lennartson, Anders
    Hakansson, Mikael
    CRYSTENGCOMM, 2009, 11 (09): : 1979 - 1986
  • [3] Five-coordinate aluminum complexes of a PNP ligand
    DeMott, Jessica C.
    Guo, Chengyun
    Foxman, Bruce M.
    Yandulov, Dmitry V.
    Ozerov, Oleg V.
    MENDELEEV COMMUNICATIONS, 2007, 17 (02) : 63 - 65
  • [4] Diferrocenyltriphosphines 1: five-coordinate ruthenium complexes
    Butler, IR
    Griesbach, U
    Zanello, P
    Fontani, M
    Hibbs, D
    Hursthouse, MB
    Malik, KLMA
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 565 (1-2) : 243 - 258
  • [5] Five-coordinate Salen(tBu) complexes of zinc
    Singer, AL
    Atwood, DA
    INORGANICA CHIMICA ACTA, 1998, 277 (02) : 157 - 162
  • [6] Absolute asymmetric synthesis of five-coordinate complexes
    Lennartson, Anders
    Hakansson, Mikael
    NEW JOURNAL OF CHEMISTRY, 2015, 39 (08) : 5936 - 5943
  • [7] Ultrafast dynamic exchange in five-coordinate complexes of ruthenium
    Porter, Tyler
    Kubiak, Clifford
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [8] Five-coordinate Pd(II) orthometallated triarylphosphite complexes
    Bedford, Robin B.
    Betham, Michael
    Butts, Craig P.
    Coles, Simon J.
    Cutajar, Marica
    Gelbrich, Thomas
    Hursthouse, Michael B.
    Scully, P. Noelle
    Wimperis, Stephen
    DALTON TRANSACTIONS, 2007, (04) : 459 - 466
  • [9] Five-coordinate hydrogen
    不详
    CHEMISTRY IN BRITAIN, 1997, 33 (08) : 15 - 15
  • [10] Recognition of Prochiral Sulfides in Five-Coordinate PtII Complexes
    Calvanese, Luisa
    Cucciolito, Maria E.
    D'Amora, Angela
    D'Auria, Gabriella
    Esposito, Antonio
    Esposito, Roberto
    Falcigno, Lucia
    Ruffo, Francesco
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (24) : 4068 - 4075
12345