Absolute asymmetric synthesis of five-coordinate complexes

被引：8
|
作者：
Lennartson, Anders [1 ]
Hakansson, Mikael [2 ]
机构：
[1] Chalmers Univ Technol, Dept Chem & Chem Engn, S-41296 Gothenburg, Sweden
[2] Univ Gothenburg, Dept Chem & Mol Biol, S-41296 Gothenburg, Sweden
来源：
NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 08期
基金：
瑞典研究理事会;
关键词：
TOTAL SPONTANEOUS RESOLUTION; X-RAY CRYSTAL; AMPLIFICATION; CHIRALITY; REAGENTS;
D O I：
10.1039/c5nj00254k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In 2009, we reported the first example of the optical resolution of a five-coordinate complex. In this study, we discuss the chirality of five-coordinate enantiomers displaying mono-and bi-dentate ligands by optical resolution of three complexes. Through total spontaneous resolution, it was possible to obtain optically active bulk products starting from achiral precursors only. It was discovered that crystallisation of two of the complexes was influenced by undetectable amounts of an unidentified source of optical activity.
引用
收藏
页码：5936 / 5943
页数：8
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