Total Spontaneous Resolution of Five-Coordinate Complexes

被引：37

作者：

Lennartson, Anders ^{[1
]}

Hakansson, Mikael ^{[1
]}

机构：

[1] Univ Gothenburg, Dept Chem, S-41296 Gothenburg, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 32期

基金：

瑞典研究理事会;

关键词：

asymmetric synthesis; chiral resolution; circular dichroism; five-coordinate complexes; structure elucidation; ABSOLUTE ASYMMETRIC-SYNTHESIS; CHIRAL-SYMMETRY-BREAKING; GRIGNARD-REAGENTS;

D O I：

10.1002/anie.200902206

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Talking about a resolution: Bulk quantities of five-coordinate complexes have been resolved for the first time using zinc and cadmium diethyldithiocarbamate species. The stereochemical outcome can be controlled by seeding with the desired isomer, giving access to either enantiomer in high enantiomeric excess and yield. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5869 / 5871

页数：3

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